Amplification Methods of Nitrogen Chains in the Synthesis of Energetic Materials

被引：0

作者：

Zhu Y. ^{[1
]}

Ding K.-W. ^{[1
,2
]}

Xiao C. ^{[3
]}

Li T.-Q. ^{[1
]}

Bu J.-H. ^{[1
]}

Liu W. ^{[1
]}

Guo S.-S. ^{[1
]}

Ge Z.-X. ^{[1
,2
]}

机构：

[1] Xi'an Modern Chemistry Research Institute, Xi'an

[2] State Key Laboratory of Fluorine & Nitrogen Chemicals, Xi'an

[3] Academy of Chinese Weapon Science, Beijing

来源：

Huozhayao Xuebao/Chinese Journal of Explosives and Propellants | 2021年 / 44卷 / 01期

关键词：

All-nitrogen material; Amplification method of nitrogen chain; N10; N11; N5; N8; Organic chemistry;

D O I：

10.14077/j.issn.1007-7812.201911017

中图分类号：

学科分类号：

摘要：

The developments of amplification methods of nitrogen chains in energetic material synthesis were reviewed. The common reactions such as substitution reactions of N-X bonds by azido groups, electro-catalytic oxidation reactions of azide ions, diazo transfer reactions of primary amines, dimerization reactions of diimine, N-amination and nitration reactions, oxidative coupling reactions of amine groups, and diazo-coupling reactions of amine groups were summarized. The mechanisms of typical amplification reactions of nitrogen chains were also introduced. The structural evolution processes of ionic nitrogen chains such as N5+, [N7O]+, N8-, and organic compounds with all-nitrogen fragments such as N3/N4/N5/N6/N7/N8/N10/N11 chains were emphatically discussed. The possible synthetic routes of N7-, N10 and N12 chains and the development trends of this research field were pointed out. With 65 references. © 2021, Editorial Board of Journal of Explosives & Propellants. All right reserved.

引用

页码：21 / 29

页数：8

共 64 条

[1] SAMARTZIS P C, WODTKE A M., All-nitrogen chemistry: How far are we from N60, International Reviews in Physical Chemistry, 25, 4, pp. 527-552, (2006)
[2] LIAN Peng, LAI Wei-peng, WANG Bo-zhou, Structures and stabilities of N5+,N5-,N8,N10 by density functional theory (DFT) method, Chinese Journal of Explosives & Propellants (Huozhayao Xuebao), 30, 5, pp. 28-31, (2007)
[3] LAUDERDALE W J, STANTON J F, BARTLETT R J., Stability and energetics of metastable molecules: Tetraazatetrahedrane (N4), hexaazabenzene (N6), and octaazacubane (N8), Journal of Physical Chemistry, 96, 3, pp. 1173-1178, (1992)
[4] ZARKO V E., Searching for ways to create energetic materials based on polynitrogen compounds, Combustion Explosion and Shock waves, 46, 2, pp. 121-131, (2010)
[5] LI Yu-chuan, PANG Si-ping, Progress of all-nitrogen ultrahigh-energetic materials, Chinese Journal of Explosives & Propellants (Huozhayao Xuebao), 35, 1, pp. 1-8, (2012)
[6] OSTMARK H., High energy density materials (HEDM): Overview, theory and synthetic efforts at FOI[J], New Trends in Research of Energetic Materials Czech Republic, pp. 231-250, (2006)
[7] EREMETS M I, GAVRILIUK A G, TROJAN I A, Et al., Single-bonded cubic form of nitrogen, Nature Materials, 3, 8, pp. 558-563, (2004)
[8] CACACE F, DE PETRIS G, TROIANI A., Experimental detection of tetranitrogen, Science, 295, 5554, pp. 480-481, (2002)
[9] DING K W, LI X W, XU H G, Et al., Experimental observation of TiN12+ cluster and theoretical investigation of its stable and metastable isomers, Chemical Science, 6, 8, pp. 4723-4729, (2015)
[10] DING K W, XU H G, YANG Y, Et al., Mass spectrometry and theoretical investigation of VNn+ (n=8, 9, and 10) clusters, The Journal of Physical Chemistry A, 122, 20, pp. 4687-4695, (2018)

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