Synthesis and Properties of 3, 3'-Bis(2-nitroamino-1, 3, 4-oxadiazol-4-yl)-5, 5'-linked-1, 2, 4-oxadiazole and Its Energetic Salts

被引：0
|
作者：
Liao, Si-Cheng [1 ]
Deng, Mu-Cong [1 ]
Song, Si-Wei [1 ]
Jin, Yun-He [1 ]
Liu, Tian-Lin [1 ]
Zhang, Qing-Hua [1 ]
机构：
[1] Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang,621999, China
来源：
Hanneng Cailiao/Chinese Journal of Energetic Materials | 2020年 / 28卷 / 07期
关键词：
A new energetic compound 3; 3'-bis(2-nitroamino-1; 3; 4-oxadiazol-4-yl)-5; 5'-linked-1; 2; 4-oxadiazole (BNOBO) was synthesized starting from glyoxime through a five-step reaction. Based on the acidity of BNOBO; three energetic salts (5-7) were obtained through the reactions between BNOBO and aqueous ammonia; hydrazine and hydroxylamine; respectively. The structures of as-synthesized compounds were characterized by single-crystal X-ray diffraction; IR; NMR and element analysis. The crystal of BNOBO ammonium salt was obtained through solvent evaporation method; the obtained results show that it belongs to a monoclinic system and C2/c space group with a=12.7490(8) nm; b=9.5957(7); nm; c=18.5965(12); V=2272.1(3) nm3 and Z=4. Their thermal stability; density; detonation properties and sensitivity were evaluated by TG/DSC analysis; densitometer; EXPLO5 v6.02 software and BAM sensitivity tester; respectively. Among these new energetic compounds; BNOBO possesses the highest measured density of 1.90 g•cm-3 and the highest onset decomposition temperature of 215℃. The calculated detonation velocity and pressure of BNOBO are as high as 8789 m•s-1 and 32.7 GPa; respectively. These new energetic compounds also exhibit relatively low mechanical sensitivities; in which energetic salt 5 display the low impact sensitivity of more than 20 J and friction sensitivity of 220 N. © 2020; Editorial Board of Chinese Journal of Energetic Materials. All right reserved;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
引用
收藏
页码：632 / 637
相关论文
共 50 条
  • [41] 2-(2′-Hydroxyphenyl)-5-(4″-nonylphenyl)-1,3,4-oxadiazole and its beryllium complex
    A. D. Beldovskaya
    G. A. Dushenko
    N. I. Vikrishchuk
    L. D. Popov
    Yu. V. Revinskii
    I. E. Mikhailov
    V. I. Minkin
    Russian Journal of General Chemistry, 2014, 84 : 171 - 172
  • [42] 3-Amino-4-[5-(chloromethyl)-1,2,4-oxadiazol-3-yl]furazan –a multifunctional synthon for the synthesis of 1,2,5-oxadiazole derivatives
    Andrei I. Stepanov
    Dmitry V. Dashko
    Elena V. Stepanova
    Chemistry of Heterocyclic Compounds, 2019, 55 : 1233 - 1244
  • [43] Synthesis and luminescent properties of 2-[2'-acyl(benzoyl)oxyphenyl]-5-(4"-nonylphenyl)-1,3,4-oxadiazole
    Mikhailov, I. E.
    Popov, L. D.
    Vikrishchuk, N. I.
    Beldovskaya, A. D.
    Revinskii, Yu. V.
    Dushenko, G. A.
    Minkin, V. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (01) : 203 - 205
  • [44] Crystal structure of hexaaqua-bis(3-(3-pyridin-4-yl-[1,2,4] oxadiazol-5-yl) propionato-κ3O, O′:O′ )-bis(3-(3-pyridin-4-yl-[1,2,4] oxadiazol-5yl) propionato-κO)-bis(3-(3-pyridin-4-yl-[1,2,4] oxadiazol-5-yl) propionato-κ2O, O′) dineodymium(III) octahydrate, C60H76N18O32Nd2
    Zhang, Fang
    Huang, Fang
    Zhang, Zhaoqun
    Lu, Yanhua
    Chen, Qifan
    Liu, Fei
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2016, 231 (04): : 1135 - 1137
  • [45] Synthesis and luminescent properties of 2-[2′-acyl(benzoyl)oxyphenyl]-5-(4″-nonylphenyl)-1,3,4-oxadiazole
    I. E. Mikhailov
    L. D. Popov
    N. I. Vikrishchuk
    A. D. Beldovskaya
    Yu. V. Revinskii
    G. A. Dushenko
    V. I. Minkin
    Russian Journal of General Chemistry, 2015, 85 : 203 - 205
  • [46] Synthesis and Antimicrobial Screening of Some Novel 2, 5-Disubstituted 1, 3, 4-oxadiazole Derivatives
    Panneerselvam, P.
    Ganesh, G. Geete
    E-JOURNAL OF CHEMISTRY, 2011, 8 : S149 - S154
  • [47] 2,5-Bis(4-methoxyphenyl)-1,3,4-oxadiazole
    Fun, Hoong-Kun
    Goh, Jia Hao
    Nithinchandra
    Kalluraya, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O3072 - U2264
  • [48] Synthesis and fungicidal activity of 4,4′-bis[(2"-arylthiazolo[4,3-b]-1,3,4-oxadiazol-5"-yl)amethoxy]bibenzyls
    Siddiqui, IR
    Dwivedi, S
    Shukla, PK
    Singh, PK
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2006, 83 (01) : 89 - 93
  • [49] Molecular mechanics study of the inclusion complexes of some 1,2,4-oxadiazole derivatives of 3,3′-bis (1,2,4-oxadiazol-5(4H)-one) with β-cyclodextrin
    Al-Sou'od, KA
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2006, 54 (1-2) : 123 - 127
  • [50] Crystal structure of 2-(adamantan-1-yl)-5-(4-bromophenyl)-1,3,4-oxadiazole
    Alzoman, Nourah Z.
    El-Emam, Ali A.
    Ghabbour, Hazem A.
    Kumar, C. S. Chidan
    Fun, Hoong-Kun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : O1231 - +
12345