Synthesis and host-guest properties of pillar[6]arenes

被引：0
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作者：
MEIER Herbert
机构：
[1] InstituteofOrganicChemistry,UniversityofMainz
来源：
Science China(Chemistry). | 2012年 / 55卷 / 02期
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摘要：
A facile method for the synthesis of pillar[6]arenes was developed.A series of pillar[6]arenes were prepared with FeCl 3 as catalyst and chloroform as solvent at room temperature in moderate yields(30%-40%).Their host-guest properties with n-cetyltrimethyl ammonium bromide were investigated by 1 HNMR.The results showed that high selectivity in the host-guest relationship became apparent between pillar[6]arenes and pillar[5]arenes based on the different size of the inner cavity.
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页数：6
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