C-H Activation via Group 8-10 Pincer Complexes: A Mechanistic Approach

被引：1

作者：

Serrano-Garcia, Juan S. ^{[1
]}

Amaya-Florez, Andres ^{[1
]}

Galindo, Jordi R. ^{[1
]}

Gonzalez-Sebastian, Lucero ^{[2
]}

Delgado-Rangel, Luis Humberto ^{[1
]}

Morales-Morales, David ^{[1
]}

机构：

[1] Univ Nacl Autonoma Mexico, Inst Quim, Ciudad Univ,Circuito Exterior S-N, Ciudad Mexico 04510, Mexico

[2] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Ave San Rafael Atlixco 186, Ciudad Mexico 09340, Mexico

来源：

INORGANICS | 2024年 / 12卷 / 08期

关键词：

C-H activation; pincer; catalysis; reaction mechanism; CATALYZED C(SP(2))-H BORYLATION; ALKANE TRANSFER-DEHYDROGENATION; BOND ACTIVATION; OXIDATIVE ADDITION; IRIDIUM COMPLEXES; NICKEL; ALKYLATION; ARENES; SELECTIVITY; CHEMISTRY;

D O I：

10.3390/inorganics12080221

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

C-H bond activation is a crucial synthetic strategy widely utilized in both academic and industrial settings. Due to the strong and kinetically inert nature of the C-H bond, its functionalization typically requires metal-based catalysts. This review highlights the most significant advancements in homogeneously catalyzed reactions using pincer complexes with metals from groups 8-10, capable of promoting challenging C-H activation, published since 2010. In particular, it focuses on C-H bond activation for borylation, isomerization, and dehydrogenation, among other processes, discussing their scope and mechanistic insights.

引用

页数：33

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