Features of Polymer Modification in a Supercritical Carbon Dioxide Environment

被引:0
|
作者
Solovieva, A. B. [1 ]
Timashev, P. S. [1 ,2 ,3 ]
机构
[1] Russian Acad Sci, Semenov Fed Res Ctr Chem Phys, Moscow, Russia
[2] Sechenov Univ, Sechenov First Moscow State Med Univ, Inst Regenerat Med, Moscow, Russia
[3] Moscow MV Lomonosov State Univ, Fac Chem, Moscow, Russia
关键词
DISPERSION POLYMERIZATION; PHOTOCHROMIC PROPERTIES; LUMINESCENT PROPERTIES; CHITOSAN IMPREGNATION; METHYL-METHACRYLATE; CONTROLLED SIZE; CO2; SOLUBILITY; STATE; NANOPARTICLES;
D O I
10.1134/S181123822460023X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Processes of polymer modification in a supercritical carbon dioxide environment leading to the production of new materials intended primarily for medicine, pharmacology, and conducting polymer systems are analyzed. The processes of polymer impregnation in a supercritical carbon dioxide environment with carbon nanotubes to produce heat- and electrically conductive polymer materials and the processes of polymer micronization used in the development of polymer-polymer composite materials are considered. The processes of obtaining aerogel materials based on polysaccharides (sodium alginate) for use as matrices for biocompatible heterogeneous catalytic systems, the processes of impregnation of thermoplastics with photochromic and luminescent compounds leading to the corresponding photoactive polymer materials, and the processes of immobilization in natural polysaccharide matrices of biologically active compounds allowing the production of prolonged medicinal products are described. Particular attention is paid to the features of graft copolymerization, which allows obtaining biocompatible products for additive technologies and completely nontoxic materials with high adhesion to cells.
引用
收藏
页码:131 / 159
页数:29
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