Exploring dissolved N2O characteristics and unearthing indirect N2O emission factors in the shallow groundwater of paddy and upland fields

Indirect emissions of nitrous oxide (N2O) stemming from nitrogen (N) leaching in agricultural fields constitute a significant contributor to atmospheric N2O. Groundwater nitrate (NO3 --N) pollution is severe in the Ningxia Yellow River Irrigation Area (NYRIA), coupled with high NO3 --N leaching, exacerbates the risk of indirect N2O emissions from groundwater. Over two years of field observations, this study investigated the characteristics and interannual variations of dissolved N2O (dN2O) concentrations and indirect N2O emission factors (EF5g) in shallow groundwater. The research focused on three typical farmlands in the NYRIA, each subjected to six levels of N fertilizer application. The mean dN2O concentrations in the groundwater of paddy, corn and vegetable fields were 5.17, 8.40 and 16.35 mu g N & sdot;L- 1, respectively. Notably, the dN2O concentrations in the shallow groundwater of upland fields exceeded those in paddy fields, with maximum levels in vegetable fields nearly an order of magnitude higher. Elevated N application significantly increased dN2O concentrations across various farmlands, showing statistically significant variation. However, differences in EF5g-A and EF5g-B within the same farmland were negligible. Denitrification was the primary process contributing to N2O production in groundwater, with nitrification also played a crucial role in upland fields. Factors such as NO3 --N, NH4+-N, dissolved oxygen (DO),