Potential for light-induced separation of critical rare-earth elements

被引:0
|
作者
Ferguson, Andrew J. [1 ]
Gish, Melissa K. [1 ]
机构
[1] Natl Renewable Energy Lab, Mat Chem & Computat Sci Directorate, Golden, CO 80401 USA
来源
TRENDS IN CHEMISTRY | 2024年 / 6卷 / 08期
关键词
METAL-ORGANIC FRAMEWORKS; TRIPLET SENSITIZATION; SOLVENT-EXTRACTION; CO2; UPTAKE; PHOTOCHEMISTRY; ADSORPTION; RECOVERY; EUROPIUM; MIXTURE; LIQUID;
D O I
10.1016/j.trechm.2024.06.006
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Current methods for separations of critical rare earth elements (REEs) require multistep, waste-generating procedures that lack the ability to selectively separate similarly sized ions, despite such an onerous process. REEs possess unique optoelectronic properties that are often exploited for photomagnetic or photoluminescent applications but could be harnessed to drive element selective separations. Recent work exploring photochemical reactions of REE complexes points to promise for investigating alternative separations using photoactive molecules and macro- molecular frameworks, highlighting a possible pathway towards realizing practical REE separations to increase the sustainability and longevity of mining and recycling these elements.
引用
收藏
页码:432 / 446
页数:15
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