Polymer time crystal: Mechanical activation of reversible bonds by low-amplitude high frequency excitations

被引:0
|
作者
Heidari, Maziar [1 ,3 ]
Gaichies, Theophile [1 ,2 ,4 ]
Leibler, Ludwik [1 ]
Labousse, Matthieu [1 ]
机构
[1] Univ PSL, ESPCI Paris, CNRS, Gulliver, F-75005 Paris, France
[2] Univ PSL, Dept Chim, Ecole Normale Super, F-75005 Paris, France
[3] Max Planck Inst Biophys, Theoret Biophys Dept, D-60438 Frankfurt, Germany
[4] Univ Paris Saclay, CNRS, Lab Phys Solides, F-91405 Orsay, France
来源
SCIENCE ADVANCES | 2024年 / 10卷 / 21期
关键词
VISCOELASTIC PROPERTIES; DYNAMIC STRENGTH; MONTE-CARLO; ADHESION; FORCE; ELASTOMERS; FIELD; MECHANOCHEMISTRY; RELAXATION; ULTRASOUND;
D O I
10.1126/sciadv.adn6107
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Reversible supramolecular bonds play an important role in materials science and in biological systems. The equilibrium between open and closed bonds and the association rate can be controlled thermally, chemically, by mechanical pulling, by ultrasound, or by catalysts. In practice, these intrinsic equilibrium methods either suffer from a limited range of tunability or may damage the material. Here, we present a nonequilibrium strategy that exploits the dissipative properties of the system to control and change the dynamic properties of sacrificial and reversible networks. We show theoretically and numerically how high-frequency mechanical oscillations of very low amplitude can open or close bonds. This mechanism indicates how reversible bonds could alleviate mechanical fatigue of materials especially at low temperatures where they are fragile. In another area, it suggests that the system can be actively modified by the application of ultrasound to induce gel-fluid transitions and to activate or deactivate adhesion properties.
引用
收藏
页数:7
相关论文
共 50 条