Non-relativistic energy spectra of O2+(X2Πg) and N2(X1Σg+) diatomic molecules confined in a modified Scarf potential via supersymmetric WKB approach

In this research, the energy equation of the Schrodinger equation with the modified Scarf potential has been obtained using the supersymmetric WKB (SWKB) approach. The Pekeris approximation has been applied to enable the analytical solution. The energy equation was applied to determine the rovibrational states of two diatomic molecules such as O-2(+)(X-2 Pi(g)) and N-2(X-1 Sigma(+)(g)) . The average kinetic and potential energies were computed via the Hellman-Feynman theorem. The analytical result of the energy equation obtained coincides with the work reported in earlier literature where the authors had applied a different approach. The energy eigenvalues for the studied molecules were found to agree with the ones obtained using the Teitz-Hua molecular potential, the deformed modified Rosen-Morse (DMRM) potential, the Morse potential and the Rydberg-Klein-Rees data points. For the energy spectra, we found average absolute deviations of 0.129515% for O-2(+)(X-2 Pi(g)) and 1.834993% for N-2(X-1 Sigma(+)(g)) molecules respectively. The energy spectra increase as the quantum numbers increase up to the dissociation limit before decreasing. For the molecules, the atoms were found to possess an oscillatory-type motion where an increase in the mean kinetic energy resulted in a decrease in mean potential energy and vice-visa.