2,3-Bis(2-pyridyl)thieno[3,4-b]pyrazine and its ruthenium(II) complexes: a new bidentate bridging ligand for enhanced metal-metal communication

被引：0
|
作者：
Konkol, Kristine L. [1 ]
Wilcox, Wyatt D. [1 ]
Rasmussen, Seth C. [1 ]
机构：
[1] North Dakota State Univ, Dept Chem & Biochem, Dept 2508,POB 6050, Fargo, ND 58108 USA
来源：
DALTON TRANSACTIONS | 2024年 / 53卷 / 40期
关键词：
INTERVALENCE CHARGE-TRANSFER; ELECTROCHEMICAL PROPERTIES; POLYNUCLEAR RUTHENIUM(II); POLYPYRIDYL COMPLEXES; EXCITED-STATE; REDOX SERIES; DINUCLEAR; MONONUCLEAR; OSMIUM(II); TRANSITION;
D O I：
10.1039/d4dt02495h
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new bidentate bridging ligand, bis(2-pyridyl)thieno[3,4-b]pyrazine is reported, along with its mono- and bi-metallic Ru(II) complexes as representative examples. Spectroscopic, electrochemical and X-ray crystallographic characterization of these species is reported, with the separation of the two Ru(III)/Ru(II) couples of the bimetallic complex suggesting better metal-metal communication than classical polypyridyl analogues.
引用
收藏
页码：16685 / 16692
页数：8
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