Reactivity of the [HFe(CO)4]-hydride for the synthesis of low coordinated phosphorus derivatives

被引：0
|
作者：
Caminade, Anne-Marie [1 ,2 ]
机构：
[1] CNRS, Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse 4, France
[2] Univ Toulouse, CNRS, LCC, Toulouse, France
来源：
INORGANICA CHIMICA ACTA | 2024年 / 573卷
关键词：
Phosphorus; Iron hydride; Complex; Diphosphene; Phosphide complex; X-RAY-STRUCTURE; VERSATILE REAGENT; CHEMISTRY; IRON; DICHLOROPHOSPHINES; PHOSPHAALKENES; REARRANGEMENT; DIPHOSPHENES; COMPLEXES; HFE(CO)4;
D O I：
10.1016/j.ica.2024.122336
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [X][Hfe(CO)(4)] (X = mainly PPh4, but also NEt4, K and Ph3PNPPh3) with chlorophosphines for the synthesis of low coordinated phosphorus complexes is reviewed. Diphosphene (-PP), phospha-alkene (PC<), phospha-allene (PCC<), and phosphide (>P) iron complexes have been in particular obtained, and characterized by P-31 NMR, and by X-ray diffraction in several cases.
引用
收藏
页数：7
相关论文
共 50 条
  • [31] Synthesis, structure, and reactivity of kinetically stabilized low-coordinated organolead compounds
    Kano, N
    Tokitoh, N
    Okazaki, R
    JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1998, 56 (11) : 919 - 930
  • [32] SYNTHESIS OF TRANSITION-METAL FORMYL COMPOUNDS BY NUCLEOPHILIC-ATTACK OF HYDRIDE ON COORDINATED CO
    CASEY, CP
    NEUMANN, SM
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (17) : 5395 - 5396
  • [33] Synthesis and mesomorphic properties of low molar mass phosphorus derivatives
    Tokushige, N
    Mihara, T
    Koide, N
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2004, 414 : 27 - 38
  • [34] SYNTHESIS OF TRIFLUOROPHOSPHINE DERIVATIVES OF COBALT TETRACARBONYL HYDRIDE BY REACTION OF METHYLSILYL COBALT TETRACARBONYL WITH PHOSPHORUS PENTAFLUORIDE
    GONDAL, SK
    MACDIARM.AG
    SAALFELD, FE
    MCDOWELL, MV
    INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1969, 5 (05): : 351 - &
  • [35] SYNTHESIS OF BENZOPHENONE BY CARBONYLATION OF IODOBENZENE WITH [BU(N)4N][HFE(CO)(4)]
    BRUNET, JJ
    ELZAIZI, A
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 486 (1-2) : 275 - 277
  • [36] REACTION OF [PPH4][HFE(CO)4] WITH DICHLOROPHOSPHINES - A NEW ENTRY TO CLASSICAL AND NONCLASSICAL FUNCTIONALIZED PHOSPHORUS COMPLEXES
    CAMINADE, AM
    MAJORAL, JP
    SANCHEZ, M
    MATHIEU, R
    ATTALI, S
    GRAND, A
    ORGANOMETALLICS, 1987, 6 (07) : 1459 - 1465
  • [37] REACTIVITY OF HFE(CO)4(-) TOWARDS PHOSPHAALKENES - A SIMPLE ROUTE TO NEW P-FUNCTIONALIZED DIPHOSPHIRANES
    CAMINADE, AM
    MAJORAL, JP
    MATHIEU, R
    KO, YYCYL
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (09) : 639 - 641
  • [38] Bis(diphosphino)methanide and hydride derivatives of Ir4(CO)12
    Detti, S
    Lumini, T
    Roulet, R
    Schenk, K
    Ros, R
    Tassan, A
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (10): : 1645 - 1648
  • [39] SYNTHESIS AND SOME REACTIONS OF CYCLIC OLIGOMERS-DERIVATIVES OF 2-COORDINATED PHOSPHORUS ATOM
    PUDOVIK, MA
    MIKHAILOV, YB
    PUDOVIK, AN
    ZHURNAL OBSHCHEI KHIMII, 1985, 55 (07): : 1475 - 1479
  • [40] SYNTHESIS, CHARACTERIZATION, AND REACTIVITY OF PPN[CR(CO)4(NO)]
    MANTELL, DR
    GLADFELTER, WL
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 347 (03) : 333 - 342
12345