Reactivity of the [HFe(CO)4]-hydride for the synthesis of low coordinated phosphorus derivatives

被引：0
|
作者：
Caminade, Anne-Marie [1 ,2 ]
机构：
[1] CNRS, Lab Chim Coordinat, 205 Route Narbonne, F-31077 Toulouse 4, France
[2] Univ Toulouse, CNRS, LCC, Toulouse, France
来源：
INORGANICA CHIMICA ACTA | 2024年 / 573卷
关键词：
Phosphorus; Iron hydride; Complex; Diphosphene; Phosphide complex; X-RAY-STRUCTURE; VERSATILE REAGENT; CHEMISTRY; IRON; DICHLOROPHOSPHINES; PHOSPHAALKENES; REARRANGEMENT; DIPHOSPHENES; COMPLEXES; HFE(CO)4;
D O I：
10.1016/j.ica.2024.122336
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [X][Hfe(CO)(4)] (X = mainly PPh4, but also NEt4, K and Ph3PNPPh3) with chlorophosphines for the synthesis of low coordinated phosphorus complexes is reviewed. Diphosphene (-PP), phospha-alkene (PC<), phospha-allene (PCC<), and phosphide (>P) iron complexes have been in particular obtained, and characterized by P-31 NMR, and by X-ray diffraction in several cases.
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页数：7
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