An Efficient Electrochemical Synthesis of Selenocarbamates from Isocyanates and Diselenides

被引：2

作者：

Zhou, Shiyu ^{[1
]}

Xiao, Qing ^{[1
]}

Guo, Li ^{[1
]}

Jin, Min ^{[1
]}

Sha, Xuelei ^{[1
]}

Yang, Jinhua ^{[1
]}

Xiao, Jiayi ^{[1
]}

Wang, Xia ^{[1
]}

Gui, Qing-Wen ^{[1
]}

机构：

[1] Hunan Agr Univ, Sch Chem & Mat Sci, Changsha 410128, Peoples R China

来源：

CHEMISTRYSELECT | 2024年 / 9卷 / 32期

基金：

中国博士后科学基金;

关键词：

Electrocatalysis; Isocyanates; Multicomponent; C-Se bonds; Selenocarbamates; ORGANOSELENIUM; SELENIUM; CATALYSTS;

D O I：

10.1002/slct.202401102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A facile electrochemical synthesis of selenocarbamates from multicomponent reactions of isocyanides, diselenides, and water is developed here. This strategy provides a mild, direct, and complementary approach for synthesizing selenocarbamates in moderate to excellent yields with good substrate tolerance. The simple undivided cell setting with carbon/Pt electrodes proceeded smoothly. A radical pathway was proposed by preliminary mechanistic research.

引用

页数：4

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