Synthesis of Diaryl Ethers via Hypervalent Iodine-Mediated C-H Functionalization

被引：0

作者：

Hu, Chenghu ^{[1
,2
,3
]}

Jia, Qi ^{[2
,3
]}

Bao, Wenjing ^{[2
,3
]}

Gu, Guangxing ^{[2
,3
]}

Li, Ya ^{[1
]}

Zhao, Yanchuan ^{[2
,3
,4
]}

机构：

[1] Shanghai Univ Engn Sci, Coll Chem & Chem Engn, Shanghai 201620, Peoples R China

[2] Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Fluorine & Nitrogen Chem & Adv Mat, Shanghai 200032, Peoples R China

[3] Chinese Acad Sci, Shanghai Hongkong Joint Lab Chem Synth, Shanghai 200032, Peoples R China

[4] Chinese Acad Sci, Shanghai Inst Organ Chem, Instrumental Anal Ctr, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 37期

基金：

中国国家自然科学基金;

关键词：

NUCLEOPHILIC AROMATIC-SUBSTITUTION; THYROID RECEPTOR LIGANDS; DIARYLIODONIUM SALTS; ARYLATION; PHENOLS; SELECTIVITY;

D O I：

10.1021/acs.orglett.4c02703

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A hypervalent iodine-reagent-based C-H functionalization strategy was utilized to synthesize diaryl ethers. This method directly transforms various arenes into their corresponding diaryliodonium salts, followed by a C-O coupling reaction to produce structurally diverse diaryl ethers. The efficacy of this approach in the late-stage structural modifications of complex molecules was demonstrated.

引用

页码：7864 / 7868

页数：5

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