Influence of silver on the luminescence of Nd3+-doped LaF3 glass-ceramics

被引:0
|
作者
Sedano, M. [1 ]
Gorni, G. [2 ]
Mather, G. C. [1 ]
Duran, A. [1 ]
Fernandez, J. [3 ]
Pascual, M. J. [1 ]
Balda, R. [4 ,5 ]
机构
[1] Inst Ceram & Vidrio ICV CSIC, C Kelsen 5, Madrid 28049, Spain
[2] Inst Opt IO CSIC, Laser Proc Grp, C Serrano 121, Madrid 28006, Spain
[3] DIPC, San Sebastian 20018, Spain
[4] Univ Pais Vasco UPV EHU, Dept Fis Aplicada, Escuela Super Ingn, Bilbao 48013, Spain
[5] UPV EHU CSIC, Ctr Fis Mat, San Sebastian 20018, Spain
关键词
Oxyfluoride glass-ceramics; Nd3+ ions; Ag-0; Metallic nanoparticles; Site-selective spectroscopy; EMISSION; NANOPARTICLES;
D O I
10.1117/12.3021998
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present study, oxyfluoride glass-ceramics (GCs) containing NdF3-doped LaF3 nanocrystals were prepared with different amounts of Ag as a co-dopant. The structural and optical properties of the GCs were characterized to identify the presence of the metallic nanoparticles, as well as their role in Nd3+ photoluminescence. Site-selective emission spectra show that Ag co-doped samples, thermally treated in an N-2 atmosphere, exhibit increased luminescence of Nd3+ ions in the crystalline phase compared to Ag-free analogues. This effect can be attributed to the local field enhancement at the LaF3 nanocrystals due to the presence of Ag-0 nanoparticles.
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页数:6
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