Thermodynamic evaluation and optimization of the K2O-Al2O3-SiO2 system

被引：0
|
作者：
Yang, Jifeng [1 ]
Yan, Lianfeng [2 ]
Ye, Lideng [1 ]
Xiao, Guangheng [1 ]
Wang, Kaige [1 ]
Liu, Yuling [2 ]
Zhang, Ligang [1 ]
Liu, Libin [1 ]
Du, Yong [2 ]
机构：
[1] Cent South Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
[2] Cent South Univ, State Key Lab Powder Met, Changsha 410083, Hunan, Peoples R China
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2024年 / 107卷 / 12期
关键词：
CALPHAD; K2O-Al2O3-SiO2; system; phase diagram; thermodynamic optimization; PHASE-TRANSITIONS; LOW ALBITE; LEUCITE; KALSILITE; BEHAVIOR; MULLITE; SILICA;
D O I：
10.1111/jace.20093
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
The K2O-Al2O3-SiO2 system is an important component of microcrystalline glass. The K2O-Al2O3 and K2O-SiO2 binary systems and the K2O-Al2O3-SiO2 ternary system were thermodynamically evaluated and optimized using the CALculation of PHAse Diagram (CALPHAD) method. The liquid phase is described by using the ionic two-sublattice model, and the solid solutions involved in the ternary system are all described using the compound energy formalism (CEF) model. The new parameters obtained from the optimization are capable of describing the equilibrium phase relations of the ternary system and its subsystems, and the calculated thermodynamic properties of the ternary compounds are in good agreement with the experimental data.
引用
收藏
页码：8732 / 8745
页数：14
相关论文
共 50 条
  • [21] MULTICOMPONENT DIFFUSION IN TERNARY SILICATE MELTS IN THE SYSTEM K2O-AL2O3-SIO2 .1. EXPERIMENTAL MEASUREMENTS
    CHAKRABORTY, S
    DINGWELL, DB
    RUBIE, DC
    GEOCHIMICA ET COSMOCHIMICA ACTA, 1995, 59 (02) : 255 - 264
  • [22] Relationship between leucite content and compressive strength of K2O-Al2O3-SiO2 system dental glass ceramics
    Zhang Biao
    Qian Fatang
    Duan Xinglong
    Wu Bolin
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2009, 24 (01): : 72 - 74
  • [23] Relationship between leucite content and compressive strength of K2O-Al2O3-SiO2 system dental glass ceramics
    Biao Zhang
    Fatang Qian
    Xinglong Duan
    Bolin Wu
    Journal of Wuhan University of Technology-Mater. Sci. Ed., 2009, 24 : 72 - 74
  • [24] Relationship between Leucite Content and Compressive Strength of K2O-Al2O3-SiO2 System Dental Glass Ceramics
    张飚
    钱法汤
    Journal of Wuhan University of Technology(Materials Science), 2009, (01) : 72 - 74
  • [25] Nonisothermal crystallization kinetics and stability of leucite and kalsilite from K2O-Al2O3-SiO2 glasses
    Christopoulou, Georgia
    Modarresifar, Farid
    Allsopp, Benjamin L.
    Jones, Alan H.
    Bingham, Paul A.
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2019, 102 (01) : 508 - 523
  • [26] Thermodynamic assessment of Al2O3-SiO2-Ce2O3 system
    Li, Yandong
    Liu, Chengjun
    Zhang, Tongsheng
    Jiang, Maofa
    Peng, Cheng
    METALLURGICAL RESEARCH & TECHNOLOGY, 2017, 114 (03)
  • [27] Thermodynamic modeling of the Al2O3-B2O3-SiO2 system
    Swamy, Varghese
    Jung, In-Ho
    Decterov, Sergei A.
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 2009, 355 (34-36) : 1679 - 1686
  • [28] MULTICOMPONENT DIFFUSION IN TERNARY SILICATE MELTS IN THE SYSTEM K2O-AL2O3-SIO2 .2. MECHANISMS, SYSTEMATICS, AND GEOLOGICAL APPLICATIONS
    CHAKRABORTY, S
    DINGWELL, DB
    RUBIE, DC
    GEOCHIMICA ET COSMOCHIMICA ACTA, 1995, 59 (02) : 265 - 277
  • [29] Critical Evaluation and Thermodynamic Optimization of the Na2O-FeO-Fe2O3-SiO2 System
    Moosavi-Khoonsari, Elmira
    Jung, In-Ho
    METALLURGICAL AND MATERIALS TRANSACTIONS B-PROCESS METALLURGY AND MATERIALS PROCESSING SCIENCE, 2016, 47 (01): : 291 - 308
  • [30] Thermodynamic optimization of the CaO-Al2O3-SiO2-MgO slag system
    Tian, Dong-Dong
    Zhang, Yan-Ling
    Liu, Qing-Bo
    Wen, Xin-Shu
    Beijing Keji Daxue Xuebao/Journal of University of Science and Technology Beijing, 2014, 36 (SUPPL.1): : 126 - 132
12345