Copper(I) Iodide-Catalyzed Perfluoroalkoxylation Reaction of Alkyl Halides

被引：1

作者：

Wu, Xiong ^{[1
]}

Le, Bingjun ^{[1
]}

Xiao, Wangchuan ^{[2
]}

Wu, Jingjing ^{[1
,2
]}

Wu, Fanhong ^{[1
,2
]}

Ma, Xiaoyu ^{[1
,2
]}

Liu, Chao ^{[1
,2
,3
]}

机构：

[1] Shanghai Inst Technol, Sch Chem & Environm Engn, Shanghai 201418, Peoples R China

[2] Shanghai Sanming Engn Res Ctr Green Fluoropharmace, Sanming 365004, Fujian, Peoples R China

[3] Chinese Acad Sci, Univ Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Fluorine & Nitrogen Chem & Adv Mat, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2024年 / 26卷 / 34期

基金：

中国国家自然科学基金;

关键词：

TRIFLUOROMETHYLTHIOLATION;

D O I：

10.1021/acs.orglett.4c02428

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report an efficient perfluoroalkoxylation reaction of alkyl halides catalyzed by copper(I) iodide (CuI), which facilitates the simultaneous activation of both perfluoroalkoxide and alkyl halides. This methodology is tolerant of a wide range of functional groups and eliminates the need for costly metal reagents. The reaction is conducted in a single step under mildly practical conditions.

引用

页码：7139 / 7143

页数：5

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