Features of Oxidation of Bismuth by High-Density Water-Oxygen Fluid

被引:2
|
作者
Fedyaeva, O. N. [1 ]
Grebennikov, A. P. [1 ]
Vostrikov, A. A. [1 ]
机构
[1] Russian Acad Sci, Kutateladze Inst Thermophys, Siberian Branch, Novosibirsk, Russia
关键词
EQUILIBRIA; CORROSION;
D O I
10.1134/S1810232824030020
中图分类号
O414.1 [热力学];
学科分类号
摘要
The paper presents the results of a study of oxidation of bulk bismuth samples by oxygen, water vapor, and water-oxygen fluid in a reactor heated to 873 K at a rate of 1 K/min with high-density reagents (rho O-2 <= 0.62 and rho H2O <= 5.24 mol/dm(3)). The results include temperature dependences of the pressure of the reaction mixtures. The rate of oxygen consumption is found from these dependences through the Redlich-Kwong equation of state. Formation of dense oxide film during the oxidation of bismuth in the O-2 environment was shown. No oxide formation was detected during treatment of bismuth with water vapor. The combined action of O-2 and H2O molecules enhances the oxidation of bismuth and leads to formation of oxides of different compositions and morphologies. At T>720 K, the bismuth oxidation rate was observed to increase due to the higher pressure of saturated bismuth vapor.
引用
收藏
页码:467 / 477
页数:11
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