Fabrication of SrSnO3/rGO composite via hydrothermal technique as robust electrocatalyst for OER process

被引:7
|
作者
Rubab, Sumia [1 ]
Alsalhi, Sarah A. [2 ]
Dahshan, A. [3 ]
Aslam, Muhammad [4 ,5 ]
Ahmad, Khursheed [6 ]
Alrowaily, Albandari. W. [2 ]
机构
[1] Govt Grad Coll Taunsa Sharif, Dept Chem, Taunsa Sharif, Pakistan
[2] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Phys, Riyadh, Saudi Arabia
[3] King Khalid Univ, Coll Sci, Dept Phys, Abha, Saudi Arabia
[4] Ural Fed Univ, Inst Phys & Technol, Ekaterinburg, Russia
[5] Gomal Univ, Dept Phys, Dera Ismail Khan, KP, Pakistan
[6] Yeungnam Univ, Sch Mat Sci & Engn, Gyongsan, South Korea
关键词
SrSnO3/rGO composite; Electrocatalyst; Hydrothermal technique; OER; OXYGEN EVOLUTION REACTION; EFFICIENT; GRAPHENE; HYBRID; PERFORMANCE; FILMS; RU;
D O I
10.1007/s10971-024-06521-7
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Developing effective and durable electrocatalysts for long-term energy conversion technologies is still an ongoing problem for researchers. For this purpose, perovskite oxides have attracted significant interest as effective electrocatalysts for oxygen evolution reactions (OER) in response to their highly adjustable catalytic and electrical properties associated with their compositions. This study presents a novel hydrothermal approach to fabricate SrSnO3/rGO composite in order to accelerate the four electron transfer mechanisms. Moreover, the physical analyses show that cubic-shaped SrSnO3 are irregularly dispersed in the form of spherical on the nanosheets of rGO. Compared with pristine, the BET study shows that composite exhibits a greater surface area (59 m(2) g(-1)). To evaluate the catalytic kinetics, conductivity and stability, the electrochemical evaluation of the electrode material (SrSnO3/rGO) was performed in alkaline media with Ni foam (NF) as substrate. The exceptional electrocatalytic performance of the material in the OER could be associated with its unique structure, many active sites, and favorable conductivity. This performance is characterized by fast reaction rates, as indicated by a minimal Tafel constant (33 mV dec(-1)) along with reduced overpotential (199 mV) at 10 mA cm(-2). Moreover, the chronoamperometry (CA) investigation of the SrSnO3/rGO composite indicates 35 h of long-term stability. This study presents a viable approach for producing high-performing perovskite composites for effective OER electrocatalysis.
引用
收藏
页码:885 / 897
页数:13
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