Stability of Supramolecular β-Cyclodextrin-Pyrene Complexes in a Silicate Hydrogel Matrix

被引:0
|
作者
Kondakova, A. V. [1 ]
Medvedeva, A. A. [1 ]
Koshkin, A. V. [1 ]
机构
[1] Russian Acad Sci, Ctr Photochem, Moscow 119421, Russia
关键词
silicate hydrogels; supramolecular complex; beta-cyclodextrin-pyrene complex; functional materials; stability; LUMINESCENT PROPERTIES; FLUORESCENCE; SPECTRA; ABSORPTION;
D O I
10.1134/S0036023624600400
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In order to use the beta-cyclodextrin-pyrene complex as a fluorescent receptor center, its stability in the solid phase of a water-soluble silicate gel was studied. For this purpose, a technique for obtaining a silicate matrix with a high content of supramolecular complexes was developed and the temperature stability of the resulting material was investigated. Optimal conditions for operating with complexes in the silica gel matrix were identified. Comparative studies of the fluorescence spectra of complexes in liquid and solid phases were carried out by the method of fluorescence spectroscopy. As a result of the work, it was possible to determine the main patterns of behavior of the supramolecular complex in the silicate hydrogel matrix and to conclude about the influence of the matrix structure on its stability.
引用
收藏
页码:546 / 550
页数:5
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