Spontaneously formed interfacial structure boosting dendrite-free Li metal batteries

被引：0

作者：

Pan, Lehao ^{[1
]}

Liu, Fengquan ^{[1
]}

Xiang, Tianqi ^{[2
]}

Dong, Chang ^{[2
]}

You, Tao ^{[1
]}

Zhang, Yuying ^{[1
]}

Wang, Chen ^{[1
]}

Li, Lin ^{[1
,2
]}

机构：

[1] Qingdao Univ, Coll Text & Clothing, State Key Lab Biofibers & Ecotext, Qingdao 266071, Peoples R China

[2] Beijing Normal Univ, Coll Chem, Beijing Key Lab Energy Convers & Storage Mat, Beijing 100875, Peoples R China

来源：

SURFACES AND INTERFACES | 2024年 / 54卷

关键词：

Recrystallization; Solid electrolyte interface; Dendrite-free Li metal batteries; LITHIUM; ELECTROLYTE;

D O I：

10.1016/j.surfin.2024.105124

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Herein a spontaneously formed solid electrolyte interface (SEI) layer with modified spherical structure is prepared by a simple strategy. Caprolactone (CL) is in-situ polymerized to polycaprolactone (PCL) after being triggered by Li metal, and turned into spherical distribution at the surface of Li after recrystallization treatment. Spontaneously formed spherical structure restrains the growth of Li dendrites and boosts homogeneous Li deposition. The Li||Li symmetrical cells present stable plating/stripping behavior at current density of 0.5 to 1.0 mA cm(-2) and exhibit excellent cycling stability. This work provides inspiration for restraining the growth of Li dendrites and building stable electrolyte/metal anode interfaces.

引用

下载

页数：6

共 50 条

[21] In Situ Formed Lithiophilic LixNbyO in a Carbon Nanofiber Network for Dendrite-Free Li-Metal Anodes
Yi, Shan
Hong, Donghui
Su, Zhe
Tian, Liying
Zhang, Wanyu
Chen, Mingqi
Hu, Mengfei
Niu, Bo
Zhang, Yayun
Long, Donghui
ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (47) : 56498 - 56509
[22] Dendrite-Free Solid-State Li Metal Batteries Enabled by Bifunctional Polymer Gel Electrolytes
Wu, Qian
Yang, Yun
Chen, Zheng
Su, Qinting
Huang, Songde
Song, Dakun
Zhu, Caizhen
Ma, Rui
Li, Cuihua
ACS APPLIED ENERGY MATERIALS, 2021, 4 (09) : 9420 - 9430
[23] Structural and Interfacial Manipulation of Multifunctional Skeletons Enabled Shuttling-Free and Dendrite-Free Li-S Full Batteries
Zhang, Miaomiao
Luo, Rongjie
Guo, Qifei
Tang, Zihuan
Li, Xingxing
Gao, Biao
Zhang, Xuming
Huo, Kaifu
Zheng, Yang
SMALL, 2023, 19 (49)
[24] Homogenous charge distribution by free-standing porous structure for dendrite-free Li metal anode
Kang, Danmiao
Tang, Kun
Koh, Joonho
Liang, Wenbin
Lemmon, John P.
JOURNAL OF ENERGY CHEMISTRY, 2020, 44 : 68 - 72
[25] Structural and Interfacial Manipulation of Multifunctional Skeletons Enabled Shuttling-Free and Dendrite-Free Li-S Full Batteries
Zhang, Miaomiao
Luo, Rongjie
Guo, Qifei
Tang, Zihuan
Li, Xingxing
Gao, Biao
Zhang, Xuming
Huo, Kaifu
Zheng, Yang
SMALL, 2023,
[26] Cotton-derived carbon cloth enabling dendrite-free Li deposition for lithium metal batteries
Meng, Jing-Ke
Wang, Wei-Wen
Yue, Xin-Yang
Xia, He-Yi
Wang, Qin-Chao
Wang, Xin-Xin
Fu, Zheng-Wen
Wu, Xiao-Jing
Zhou, Yong-Ning
JOURNAL OF POWER SOURCES, 2020, 465
[27] Surface Coating on a Separator with a Reductive Solid Li-Ion Conductor for Dendrite-Free Li-Metal Batteries
Huang, Bing
Luo, Jiangbin
Xu, Biyi
Li, Zhihong
Li, Yutao
Che, Yong
Wang, Chang-An
ACS APPLIED ENERGY MATERIALS, 2021, 4 (08) : 8621 - 8628
[28] Introducing Crown Ether as a Functional Additive for High-Performance Dendrite-free Li Metal Batteries
Zhao, Jin
Li, Qingling
Pang, Yudong
Lu, Zhansheng
Wu, Jiawei
Zhao, Xiaohua
Lou, Xiangdong
Yang, Shuting
Liu, Yang
Qiao, Yun
ACS APPLIED ENERGY MATERIALS, 2021, 4 (08) : 7829 - 7838
[29] Dendrite-Free Epitaxial Growth of Lithium Metal during Charging in Li-O2 Batteries
Xin, Xing
Ito, Kimihiko
Dutta, Arghya
Kubo, Yoshimi
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2018, 57 (40) : 13206 - 13210
[30] Homogenous charge distribution by free-standing porous structure for dendrite-free Li metal anode
Danmiao Kang
Kun Tang
Joonho Koh
Wenbin Liang
John P.Lemmon
Journal of Energy Chemistry, 2020, 44 (05) : 68 - 72

← 1 2 3 4 5 →