Brass corrosion - dezincification in hydrochloric acid

被引:0
|
作者
Fickenscher, Thomas [1 ]
Schroeer, Jasmin [1 ]
Reckeweg, Olaf [2 ]
Poettgen, Rainer [1 ]
机构
[1] Univ Munster, Inst Anorgan & Analyt Chem, Corrensstr 30, D-48149 Munster, Germany
[2] Gymnasium Ernestinum Rintein, Paul Erdniss Str 1, D-31737 Rinteln, Germany
关键词
acidic corrosion; demonstration experiments; electrochemistry;
D O I
10.1515/znb-2024-0052
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Brass is among the utility metals for daily life. We present an easy corrosion experiment for demonstration in high school or first-year undergraduate studies. Almost any kind of brass can be dezincified in 1 m hydrochloric acid. Copper as the noble component remains as salmon pink coating on the workpiece while zinc and lead, the latter being a frequent minor alloying component of brass, are dissolved. Lead can be detected as PbS (in-situ generation of H2S from a splinter of FeS or as PbI2 using KI). Zinc can be analyzed as Rinmann's green or via a microchemical drop reaction with dithizone.
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页数:5
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