(Diethylamino)sulfur trifluoride (DAST)-mediated oxidation of benzylic alcohols and amines to carbonyl compounds

被引：0

作者：

Smeyne, Dylan ^{[1
]}

Boyles, Steven ^{[1
]}

Belloso, Ricardo ^{[1
]}

Verboom, Katherine ^{[1
]}

White, Bryce ^{[1
]}

Shaikh, Abid ^{[1
]}

机构：

[1] Georgia Southern Univ, Dept Chem, 521 Coll Educ Dr, Statesboro, GA 30458 USA

来源：

SYNTHETIC COMMUNICATIONS | 2024年 / 54卷 / 18期

关键词：

Aldehydes; benzyl alcohol; DAST; DMSO; oxidation; DIMETHYL-SULFOXIDE; AEROBIC OXIDATION; TEMPO; DERIVATIVES; ALDEHYDES; MECHANISM;

D O I：

10.1080/00397911.2024.2397499

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We report an efficient protocol for oxidation of primary/secondary benzyl alcohols and benzylamines to produce corresponding aldehydes or ketones. Our unified method involves the use of commercially available (diethylamino)sulfur trifluoride (DAST) as a reagent combined with DMSO as solvent and oxidant. The reaction provided corresponding carbonyl compounds in good to excellent yields with high purity and in short reaction times. GRAPHICAL ABSTRACT

引用

页码：1620 / 1628

页数：9

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