2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-Dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride

被引：0
|
作者：
Guillarme, Stephane [1 ]
Saluzzo, Christine [1 ]
机构：
[1] Le Mans Univ, Inst Mol & Materiaux Mans IMMM, MSO, CNRS ,UMR 6283, Ave O Messiaen, F-72085 Le Mans 9, France
来源：
MOLBANK | 2024年 / 2024卷 / 02期
关键词：
isosorbide; isohexide; optical active PCN pincer palladium(II) complex; phosphinite; imine; sustainable material; PINCER COMPLEXES; PLATINUM; ISOHEXIDES; CATALYSIS; PALLADIUM; VERSATILE; LIGANDS;
D O I：
10.3390/M1838
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An unsymmetrical PCN palladium pincer complex 2-{(E)-{{(R)-1-[(1R,5S,6R)-3,3-dimethyl-2,4,7-trioxabicyclo[3.3.0]octan-6-yl]ethyl}imino}methyl}-6-{[(diphenylphosphino)oxy] phenyl}palladium(II) chloride based on an iminophosphinite ligand bearing two fused five-membered cycles, one of which containing a THF ring, was prepared in an eight-reaction sequence from a sustainable and enantiopure starting material, isosorbide, in a 20% overall yield.
引用
收藏
页数：5
相关论文
共 50 条
  • [41] Approaches to the Assembly of the Antifungal Agent FR-900848: Studies on the Asymmetric Synthesis of Bicyclopropanes and an X-Ray Crystallographic Analysis of (4R,5R)-2-[(1R,3S,4S,6R)-6-Phenyl-1- bicyclopropyl]-1,3-dimethyl-4,5-diphenylimida zolidine
    Barrett, A. G. M.
    Doubleday, W. W.
    Tustin, G. J.
    White, A. J. P.
    Journal of Automatic Chemistry, 1600, 16 (43):
  • [42] APPROACHES TO THE ASSEMBLY OF THE ANTIFUNGAL AGENT FR-900848 - STUDIES ON THE ASYMMETRIC-SYNTHESIS OF BICYCLOPROPANES AND AN X-RAY CRYSTALLOGRAPHIC ANALYSIS OF (4R,5R)-2-[(1R,3S,4S,6R)-6-PHENYL-1-BICYCLOPROPYL]-1,3-DIMETHYL-4,5-DIPHENYLIMIDAZOLIDINE
    BARRETT, AGM
    DOUBLEDAY, WW
    TUSTIN, GJ
    WHITE, AJP
    WILLIAMS, DJ
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (15) : 1783 - 1784
  • [43] (1R,5S)-6-(4-Methyl-2-oxo-2,5-dihydrofuran-3-yl)-3-phenyl-4-oxa-2,6-diazabicyclo[3.2.0]hept-2-en-7-one
    Fu, Dong-Jun
    Pham, Victor
    Tippin, Matthew-Alexander
    Song, Liankun
    Zi, Xiaolin
    Zhang, En
    Liu, Hong-Min
    MOLBANK, 2018, (03)
  • [44] Convenient synthesis of (2S,3R,4R,5S,6R)-2-(3-(4-ethylbenzyl)-4-chlorophenyl)-6-(hydroxymethyl)-tetrahydro-2H-pyran-3,4,5-triol
    Yong Hai Liu~a Da Li Li~(a
    Chinese Chemical Letters, 2008, (07) : 814 - 816
  • [45] Convenient synthesis of (2S,3R,4R,5S,6R)-2-(3-(4-ethylbenzyl)-4-chlorophenyl)-6-(hydroxymethyl)-tetrahydro-2H-pyran-3,4,5-triol
    Liu, Yong Hai
    Li, Da Li
    Lu, Lu De
    Miao, Zhen Yuan
    CHINESE CHEMICAL LETTERS, 2008, 19 (07) : 814 - 816
  • [46] (-)-(1S,4S,6R,8R)-[11,11-Dimethyl-5-(4tolylsulfonyl)-3-oxa-5-azatricyclo[6.2.1.01,6]undec-4-yl](phenyl)methanone
    Ko, Kwang-Youn
    Yun, Hoseop
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4712 - U5071
  • [47] (2S)-2-[(2S*,5R*,6R*)-5,6-Dimethoxy-5,6-dimethyl-1,4-dioxan-2-yl]-1-[(S)-1,1-dimethylethylsulfonyl]aziridine
    Sola, Toni Moragas
    Lewis, William
    Bettigeri, Sampada V.
    Stockman, Robert A.
    Forbes, David C.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O3335 - U2141
  • [48] SYNTHESIS OF (+)-1,3-2,5-DIANHYDROVIBURNITOL ((+)-(1R,2R,3S,5R,6S)-4,7-DIOXATRICYCLO[3.2.1.0/3,6]OCTAN-2-OL)
    LEDRIAN, C
    VOGEL, P
    HELVETICA CHIMICA ACTA, 1988, 71 (06) : 1399 - 1405
  • [49] (1R,2R,3R,4S,5S)-3-Methyl-8-oxabicyclo[3.2.1]oct-6-ene-2,4-diyl diacetate
    Tafeenko, Viktor A.
    Aslanov, Leonid A.
    Proskurnina, Marina V.
    Sosonyuk, Sergei E.
    Khlevin, Dmitrii A.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2127 - U1347
  • [50] ALKYLATION OF (1S,2R,5R,6S,7R)- AND (1R,2R,5R,6S,7S)-5-METHYL-4-OXATRICYCLO-[5.2.1.0/2,6]-8-DECEN-3-ONE - APPLICATION TO THE SYNTHESIS OF (R)-3-ALKYL-5-METHYL-2(5H)-FURANONES
    CORBERA, J
    FONT, J
    MONSALVATJE, M
    ORTUNO, RM
    SANCHEZFERRANDO, F
    JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (18): : 4393 - 4395
12345