Photoprocesses in Bis-Diethylamino Derivatives of 1,4-and 1,3-Distyrylbenzene

被引：0

作者：

Atabekyan, Levon S. ^{[1
]}

Avakyan, Vitaly G. ^{[1
]}

Fomina, Marina V. ^{[1
]}

Nuriev, Vyacheslav N. ^{[1
,2
]}

Medved'ko, Alexey V. ^{[1
,3
]}

Vatsadze, Sergey Z. ^{[2
,3
]}

Gromov, Sergey P. ^{[1
,2
]}

Chibisov, Alexander K. ^{[1
]}

机构：

[1] NRC Kurchatov Inst, Photochem Ctr, Kurchatov Complex Crystallog & Photon, Novatorov Str 7A-1, Moscow 119421, Russia

[2] M V Lomonosov Moscow State Univ, Dept Chem, Build 3,1 Leninskie Gory, Moscow 119991, Russia

[3] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninskii Prospekt, Moscow 119991, Russia

来源：

MOLECULES | 2024年 / 29卷 / 17期

基金：

俄罗斯科学基金会;

关键词：

distyrylbenzene; fluorescence; laser photolysis; triplet-triplet dismutation; radical species; PHOTOCHEMISTRY; THIOANALOGS; FLUORESCENT; ION;

D O I：

10.3390/molecules29174139

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

The photoprocesses of diethylamino derivatives of 1,4- and 1,3-distyrylbenzenes in MeCN were studied using absorption, luminescence, 1H NMR, and laser kinetic spectroscopy. Compounds 1 and 2 undergo intersystem crossing to the triplet state and exhibit delayed fluorescence. It was concluded that dye radical anions and radical cations are formed upon dismutation of the triplet state in the presence of an electron donor or acceptor. Quantum mechanical calculations for the structures of diethylamino distyrylbenzenes in the ground and excited states were carried out, making it possible to establish the structures of isomers and the most stable conformers for both compounds.

引用

页数：17

共 50 条

[21] HYDROSILYLATION OF 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE
KUSUMOTO, T
HIYAMA, T
CHEMISTRY LETTERS, 1985, (09) : 1405 - 1408
[22] PHOTOCHEMISTRY OF 1,2-DISTYRYLBENZENE DERIVATIVES
OPDENBROUW, PM
LAARHOVEN, WH
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (08): : 1546 - 1555
[23] 1,4-phenylenediisothiocyanate in the synthesis of bis-(thiourea, benzothiazole, quinazoline, 1,3-benzoxazine and imidazolidineiminothiones) derivatives
El-Sharief, AMS
Ammar, YA
Zahran, MA
Sabet, HK
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2004, 179 (02) : 267 - 275
[24] EMISSION STUDIES OF 1,4-BIS(HETEROARYL)-1,3-BUTADIYNES
SEKHER, P
TALWAR, SS
KAMATH, MB
BABU, KN
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1990, 55 (01) : 71 - 86
[25] CARBOMETALLATION OF 1,4-BIS(TRIMETHYLSILYL)-1,3-BUTADIYNE WITH TRIMETHYLALUMINUM
KUSUMOTO, T
NISHIDE, K
HIYAMA, T
CHEMISTRY LETTERS, 1985, (09) : 1409 - 1410
[26] Efficient electroluminescent material for light-emitting diodes from 1,4-distyrylbenzene derivatives
Luo, FT
Tao, YT
Ko, SL
Chang, HC
Chen, H
JOURNAL OF MATERIALS CHEMISTRY, 2002, 12 (01) : 47 - 52
[27] Discrimination of β-1,4-and β-1,3-Linkages in Native Oligosaccharides via Charge Transfer Dissociation Mass Spectrometry
Buck-Wiese, Hagen
Fanuel, Mathieu
Liebeke, Manuel
Hoang, Kim Le Mai
Pardo-Vargas, Alonso
Seeberger, Peter H.
Hehemann, Jan-Hendrik
Rogniaux, Helene
Jackson, Glen P.
Ropartz, David
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2020, 31 (06) : 1249 - 1259
[28] SYNTHESIS OF BICYCLOBUTYLIDENE, 1,3-BIS(TRIMETHYLENE)PROPADIENE, AND 1,4-BIS(TRIMETHYLENE)BUTATRIENE
BEE, LK
BEEBY, J
EVERETT, JW
GARRATT, PJ
JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (15): : 2212 - 2214
[29] Study of 1,3-Dipolar Cycloaddition and Ring Contraction of New 1,4-Phenylene-bis[1,5]benzothiazepine Derivatives
Chen, Fei
Liu, Fang-Ming
Dong, Zhi-Qiang
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2014, 51 (06) : 1764 - 1769
[30] photonics of bis(18-crown-6)-1,4-distyrylbenzene and Its complexes with metal perchlorates
Atabekyan, L. S.
Avakyan, V. G.
Chibisov, A. K.
Gromov, S. P.
Vatsadze, S. Z.
Nuriev, V. N.
Medved'ko, A. V.
HIGH ENERGY CHEMISTRY, 2019, 53 (02) : 115 - 124

← 1 2 3 4 5 →