Delocalized spin states at zigzag termini of armchair graphene nanoribbon

被引:0
|
作者
Scepanovic, Stefan [1 ,2 ]
Kimouche, Amina [3 ]
Mirkovic, Jovan [2 ]
Sadiek, Gehad [4 ]
Klamroth, Tillmann [5 ]
Hassanien, Abdou [1 ]
机构
[1] Jozef Stefan Inst, 39 Jamova, Ljubljana 1000, Slovenia
[2] Univ Montenegro, Fac Sci, Podgorica 81000, Montenegro
[3] Univ Potsdam, Inst Phys & Astron, D-14476 Potsdam, Germany
[4] Univ Sharjah, Dept Appl Phys & Astron, Sharjah 27272, U Arab Emirates
[5] Univ Potsdam, Inst Chem, D-14476 Potsdam, Germany
来源
SCIENTIFIC REPORTS | 2024年 / 14卷 / 01期
关键词
Graphene nanoribbon; Spin states; Kondo effect; Spin-spin correlations; EDGE STATE; SHAPE;
D O I
10.1038/s41598-024-62624-9
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Using scanning tunneling microscopy and spectroscopy we demonstrate a revival of magnetism in 7-armchair nanoribbon by unpassivated atoms at the termini. Namely, a pair of intense Kondo resonances emerges at the peripheries of zigzag terminus revealing the many-body screening effects of local magnetic moments. Although Kondo resonance originates from a missing local orbital, it extends to a distance of 2.5 nm along the edge of the ribbon. The results are complemented by density functional theory calculations which suggest a possible coupling between Kondo states despite screening effects of substrate electrons. These findings indicate a possibility to restore intrinsic magnetic ordering in graphene nanoribbon without major structural modifications.
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页数:8
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