Synthesis of 1-adamantyl-4-alkyl-1 H-1,2,3-triazoles under thermal and microwave conditions

被引：0

作者：

Aminov, Rishat I. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Petrochemi & Catalysis, Ufa Fed Res Ctr, Ufa 450075, Russia

来源：

MENDELEEV COMMUNICATIONS | 2024年 / 34卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

adamantane; 1,2,3-triazoles; azides; click chemistry; ionic liquids; microwave irradiation; IONIC LIQUIDS; BINOR-S; CYCLOADDITIONS; ALKYLATION; CHEMISTRY; SALTS;

D O I：

10.1016/j.mencom.2024.04.030

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aluminate ionic liquid [Et 3 NH] + [Al 2 Cl 7 ] - was found to be an effective catalyst for the reactions of haloadamantanes with trimethylsilyl azide to produce the corresponding azidoadamantanes in 92-98% yields. Using 'click chemistry', the thus obtained azidoadamantanes were reacted with terminal alkynes under thermal or microwave conditions to cleanly afford the expected 1,4-disubstituted 1,2,3-triazoles some of which were new.

引用

页码：406 / 408

页数：3

共 50 条

[21] Magnetically recoverable copper ferrite catalyzed cascade synthesis of 4-Aryl-1H-1,2,3-triazoles under microwave irradiation
Bhuyan, Pubanita
Bhorali, Pratiksha
Islam, Imdadul
Bhuyan, Amar Jyoti
Saikia, Lakhinath
TETRAHEDRON LETTERS, 2018, 59 (16) : 1587 - 1591
[22] Progress in the Synthesis of Fused 1,2,3-Triazoles
Kumar, Hariom
Dhameja, Manoj
Rizvi, Marziya
Gupta, Preeti
CHEMISTRYSELECT, 2021, 6 (20): : 4889 - 4947
[23] SYNTHESIS OF SOME 1,2,3-TRIAZOLES DERIVATIVES
Bouasla, Souad
Fatmi, Chames Eddyn
Teguiche, Mabrouk
REVUE ROUMAINE DE CHIMIE, 2012, 57 (12) : 1037 - 1040
[24] Another Way to the Synthesis of 1,2,3-Triazoles
Xu, Beihua
Hu, Yongzhou
JOURNAL OF HETEROCYCLIC CHEMISTRY, 2013, 50 (05) : 1217 - 1222
[25] Greener synthesis of substituted 1,2,3-triazoles
Kellen-Yuen, Cynthia
Raikevitch, Cathleen
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2006, 231
[26] SUBSTITUENT EFFECTS ON POLAROGRAPHIC-REDUCTION OF 1-AMINO-4-ARYL-1,2,3-TRIAZOLES AND 1H-4-ARYL-1,2,3-TRIAZOLES
HAUPTMANN, S
WILDE, H
ZEITSCHRIFT FUR CHEMIE, 1976, 16 (07): : 280 - 281
[27] An Organocatalytic Regiospecific Synthesis of 1,5-Disubstituted 4-Thio-1,2,3-triazoles and 1,5-Disubstituted 1,2,3-Triazoles
Ramachary, Dhevalapally B.
Krishna, Patoju M.
Gujral, Jagjeet
Reddy, G. Surendra
CHEMISTRY-A EUROPEAN JOURNAL, 2015, 21 (47) : 16775 - 16780
[28] Synthesis and biological activity of glycosyl-1H-1,2,3-triazoles
Slamova, Kristyna
Marhol, Petr
Bezouska, Karel
Lindkvist, Lise
Hansen, Signe G.
Kren, Vladimir
Jensen, Henrik H.
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 2010, 20 (14) : 4263 - 4265
[29] A convenient synthesis of 5-substituted 1-[1-(diethoxyphosphoryl)alkyl]-1H-1,2,3-triazoles
Sikora, D
Gajda, T
SYNTHETIC COMMUNICATIONS, 1998, 28 (07) : 1215 - 1222
[30] MICROWAVE ASSISTED NEAT SYNTHESIS OF 1,2,3-TRIAZOLES BEARING PYRAZOLE MOIETY
Manju, N.
Kalluraya, Balakrishna
Asma
Kumar, Madan S.
HETEROCYCLIC LETTERS, 2018, 8 (03): : 619 - 629

← 1 2 3 4 5 →