Electron density in a non-thermal atmospheric discharge in contact with water and the effect of water temperature on plasma-water interactions

In this study the electron density of an atmospheric plasma generated between a pin electrode and a water surface is measured by determining the Stark broadening of H alpha and H beta emission lines. Comparable values for the electron density are achieved using the H alpha and H beta broadening obtained in separate measurements. During the temporally evolving system, increasing electron densities are measured of 0.5-3 & sdot;1015 cm-3 during the plasma treatment of 5-10 min. The effect of the water temperature on plasma-water interaction is investigated by heating the water to approximate to 70 degrees C prior to the measurements. This resulted in higher gas temperatures during the discharge up to 2500 K and 4000 K for positively and negatively pulsed discharge, respectively. Furthermore, an earlier increase of electron density and conductivity of the water is measured for the preheated experiments. The humidity of the gas is likely to be an important parameter causing the observed results.