Diagrammatic representation and nonperturbative approximations of the exact time-convolutionless master equation

被引:0
|
作者
Gu, Bing [1 ,2 ,3 ]
机构
[1] Westlake Univ, Dept Chem, Hangzhou 310030, Zhejiang, Peoples R China
[2] Westlake Univ, Dept Phys, Hangzhou 310030, Zhejiang, Peoples R China
[3] Westlake Inst Adv Study, Inst Nat Sci, Hangzhou 310024, Zhejiang, Peoples R China
来源
JOURNAL OF CHEMICAL PHYSICS | 2024年 / 160卷 / 20期
基金
中国国家自然科学基金;
关键词
QUANTUM;
D O I
10.1063/5.0187191
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The time-convolutionless master equation provides a general framework to model the non-Markovian dynamics of an open quantum system with a time-local generator. A diagrammatic representation is developed and proven for the perturbative expansion of the exact time-local generator for an open quantum system interacting with arbitrary environments. A truncation of the perturbation expansion leads to perturbative time-convolutionless quantum master equations. We further introduce a general iterative approach to construct nonperturbative approximations for the time-local generator as nested time-ordered exponential operators.
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页数:7
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