Advancing carbohydrate functionality: The role of hypervalent iodine

被引：1
|
作者：
Upadhyaya, Kapil [1 ]
Dubbu, Sateesh [2 ]
机构：
[1] Oregon Hlth & Sci Univ, Dept Chem Physiol & Biochem, Portland, OR 97239 USA
[2] Univ Illinois, Dept Chem, Roger Adams Lab, Urbana, IL 61801 USA
来源：
CARBOHYDRATE RESEARCH | 2024年 / 542卷
关键词：
Functionalization of glycals; Hypervalent iodine; Carbohydrates; CH or NH insertion reaction; IODINE(III)-PROMOTED OXIDATION; ATOM-TRANSFER; GLYCOSYLATION; IMINOSUGARS; GLYCOSIDES; AMINATION; RADICALS; REAGENTS; GLYCALS; SYSTEMS;
D O I：
10.1016/j.carres.2024.109175
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
Hypervalent iodine reagents have undergone significant development and widespread application in the functionalization of carbohydrates. This is primarily attributed to their exceptional properties, including mildness, ease of handling, high selectivity, environmental friendliness, and stability. This review aims to emphasize the utilization of hypervalent iodine compounds in the functionalization of carbohydrates. The present article covers various aspects, including glycal functionalization, C-H or N-H insertion reactions, O-arylations, C-2 deoxy-2iodo glycoconjugates, iminosugars, and C3-oxo-glycals, achieved through the use of hypervalent iodine reagents/catalysts. Additionally, it explores hypervalent iodine-mediated bioactive 1,3,5-trioxocane synthesis followed by rare sugars synthesis.
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页数：15
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