Size-Dependent Optical Properties and Exciton Self-Trapping Emission in Carbon Quantum Dots

Carbon quantum dots (CQDs), synthesized through controlled microplasma treatment of orange juice, exhibit unique luminescent characteristics. The impact of synthesis time on particle size was investigated. Deconvoluted emission spectra displayed broad bands, peaking at an excitation wavelength of 350 nm for CQD sizes of 2.06, 2.4, and 3.09 nm, indicating multiple fluorescence peaks. This suggests a mixture of CQDs with different excitation energies on their surfaces. Luminescence kinetics unveiled three exponential decay components with time constants of 2.73, 4.61, and 3.27 ns, indicating multiple luminescent centers. Emission behavior affected by excitation wavelengths ranging from 350 to 490 nm suggests that quantum transition probabilities are influenced by impurities or defects. These findings emphasize the size-dependent optical properties and exciton self-trapping (EST) emission of CQDs. The calculation of the Huang-Rhys factor S values underscores the profound influence of carrier-phonon coupling and the Huang-Rhys factor on the emergence of ESTs within CQDs. Understanding these interactions is crucial for fully utilizing the capabilities of CQDs in applications spanning optoelectronics, sensors, bioimaging, and various technological fields. Carbon quantum dots (CQDs) synthesized from orange juice via microplasma treatment exhibit diverse luminescent properties, including size-dependent optical characteristics and exciton self-trapping (EST) emission. The Huang-Rhys factor S values underscore the significant impact of carrier-phonon coupling on ESTs within CQDs. Their excitation-dependent emission and quantum transition probabilities enhance their potential in optoelectronics, sensors, and bioimaging. The highlights of the research are summarized in the chart below image