Surface chemistry and flotation properties of galena and pyrite particles in the presence of xanthate- monothiophosphatethiocarbamate collectors

被引:0
|
作者
Ercelik, Gokhan [1 ]
Terzi, Mert [1 ]
Kursun, Ilgin [1 ]
Ozdemir, Orhan [2 ]
机构
[1] Istanbul Univ Cerrahpasa, Dept Min Engn, Buyukcekmece, Istanbul, Turkiye
[2] Istanbul Tech Univ, Dept Mineral Proc Engn, Maslak, Istanbul, Turkiye
来源
PHYSICOCHEMICAL PROBLEMS OF MINERAL PROCESSING | 2023年 / 59卷 / 05期
关键词
pyrite; galena; zeta potential; bubble -particle attachment time; micro; -flotation; SULFIDE MINERALS; INDUCTION TIME; AIR BUBBLES; ATTACHMENT; ADSORPTION; KINETICS; THIONOCARBAMATE; HYDROPHOBICITY; SEPARATION; CARBONATE;
D O I
10.37190/ppmp/167947
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, surface chemistry and flotation properties of the gold -bearing galena and pyrite minerals of Menderes region, Izmir, Turkey were investigated with the use of xanthate-thiocarbamatemonothiophosphate collectors. In this context, the micro -flotation experiments, the zeta potential, and bubble -particle attachment time measurements were conducted in the presence of Thiophosphate (Aero S-8045), Xanthate (SIBX), and Thiocarbamate (Aero float MX -505) collectors. In the case of microflotation experiments, the MX -505 exhibited higher flotation efficiency for both minerals compared to SIBX and S-8045 collectors. In the micro -flotation tests conducted on galena and pyrite, while the flotation recovery of 99.82% and 81.96% were obtained with MX -505, the flotation recovery of 89.64% and 62.50% were reached in the case of using SIBX. Furthermore, the S-8045 resulted in the flotation recovery s of 75.09% and 25.45% for galena and pyrite, respectively. In the case of zeta potential experiments as a function of pH, the galena mineral showed a negative charge between -17.22 to -41.42 mV at pH 5 - 11, no point of zero charge (pzc) was determined, and the pzc of pyrite was determined as pH approximate to 8. The bubble -particle attachment time experiments performed in the presence of S-8045, SIBX, and MX -505 collectors indicated that the attachment efficiency was 100% in the presence of MX -505 at 12.5-75 g/Mg dosages and 1-1000 ms contact times. These results revealed that there was an extraordinarily strong interaction between the galena/pyrite and the air bubbles in the presence of MX505. The results obtained within this study indicated that galena and pyrite minerals showed inherently less than 25% natural floatability which can only be enhanced under specific conditions. The results obtained within this study indicated that galena and pyrite minerals showed inherently low natural floatability which can only be enhanced under specific conditions. In the tests conducted on these minerals, galena mineral showed higher than %20 natural floatability compared to pyrite mineral, and collectors produced from thiocarbamates have shown greater effectiveness compared to xanthate and thiophosphate.
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页数:16
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