High-pressure gallium seeder for atomic fluorescence measurements

This work presents the design and testing of a seeder based on laser ablation capable of introducing gallium particles into a gaseous flow at elevated pressures typical of that found in practical combustion devices. The ability to seed such a flow with gallium particles is required to apply Ga-TLAF, a spatially and temporally resolved thermometry imaging technique well suited to harsh combustion environments. The design criteria for this gallium particle seeder are first listed and all the necessary details required to understand and replicate it are then provided. Next, the efficiency of gallium ablation is verified as a function of the ablation laser's fluence and repetition rate and of the pressure using gallium laser induced fluorescence and laser scattering measurements at similar to 403 nm. For the conventional 355-nm nanosecond, Nd:YAG laser used for ablation in this study, data show that the quantity of gallium seeded into the flow can be conveniently modulated by varying the fluence of the ablation laser and/or its repetition rate. Data also show that the efficiency of ablation is marginally better for solid gallium than for liquid gallium, but that ablation of liquid gallium should be preferred to avoid a loss of ablation efficiency after some time. The temperature of the liquid gallium feedstock is found to be unimportant. SEM, EDX, and SPMS analyses show that laser ablation yields pure gallium particles with a characteristic size ranging at least from 50 nm to 10 mu m and that the size distribution is insensitive to the pressure and to the ablation laser's fluence. Also important for future applications of Ga-TLAF in high-pressure flames, data show that the gallium LIF intensity recorded at room temperature or in the hot products of a flame is not significantly affected by pressure.