Fabrication of MoS2 restrained magnetic chitosan polysaccharide composite for the photocatalytic degradation of organic dyes

被引:9
|
作者
Sirajudheen, Palliyalil [1 ]
Vigneshwaran, Sivakumar [2 ]
Thomas, Nygil [3 ]
Selvaraj, Manickam [4 ]
Venkatesan, Kumar [5 ]
Park, Chang Min [6 ]
机构
[1] Pocker Sahib Mem Orphanage Coll, Dept Chem, Malappuram 676306, Kerala, India
[2] Kyung Hee Univ, Dept Civil Engn, Environm Syst Lab, Global Campus,1732 Deogyong Daero, Yongin 16705, Gyeonggi Do, South Korea
[3] Nirmalagiri Coll, Dept Chem, Nirmalagiri PO, Kannur 670701, Kerala, India
[4] King Khalid Univ, Fac Sci, Dept Chem, Abha 61413, Saudi Arabia
[5] King Khalid Univ, Coll Pharm, Dept Pharmaceut Chem, Abha 61413, Saudi Arabia
[6] Kyungpook Natl Univ, Dept Environm Engn, 80 Daehak Ro, Daegu 41566, South Korea
基金
新加坡国家研究基金会;
关键词
Chitosan matrix; Magnetic composite; Metal sulphide; Iron oxide; Dye degradation; GRAPHENE OXIDE NANOSHEET; ANTIBACTERIAL ACTIVITY; REMOVAL ABILITY; LIGHT; NANOCOMPOSITE; PERFORMANCE; ADSORPTION; SUNLIGHT; NANOPARTICLES; MECHANISM;
D O I
10.1016/j.carbpol.2024.122071
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Chitosan (CS) polysaccharide is expected to exhibit greater ionic conductivity, which can be attributed to its increased amino group content when it is blended with different semiconducting materials. Herein, the work used this conducting ability of chitosan and prepared a heterogeneous MoS2-induced magnetic chitosan (MF@CS) composite via the co-precipitation method, which was used to scrutinize the catalytic performance with Methylene Blue (MB) and Malachite Green (MG) dyes by visible light irradiation. The saturation magnetization value of the MF@CS composite is found to be 7.8 emu/g, which is less when compared to that of pristine Fe3O4 (55.7 emu/g) particles. The bandgap of the MF@CS composite is similar to 2.17 eV, which exceeds the bandgap (E-g) of bare MoS2 of 1.80 eV. The maximum color removal of 96.3 % and 93.4 % for MB and MG dyestuffs is recognized in the exposure of the visible spectrum, respectively. At a starting dye dosage of 30 mg/L, 0.1 g/L of MF@CS, a pH level of 8-11, and 70 min of contact with direct light. The photocatalyst provides extremely good durability for a maximum of five phases. Hence, the MF@CS matrix is a viable and appropriate substance for the efficient treatment of effluents containing dye molecules.
引用
收藏
页数:12
相关论文
共 50 条
  • [41] Fabrication of Z-scheme Ag3PO4/MoS2 composites with enhanced photocatalytic activity and stability for organic pollutant degradation
    Zhu, Chaosheng
    Zhang, Lu
    Jiang, Bo
    Zheng, Jingtang
    Hu, Ping
    Li, Sujuan
    Wu, Mingbo
    Wu, Wenting
    APPLIED SURFACE SCIENCE, 2016, 377 : 99 - 108
  • [42] Preparation of CdS/RGO/MoS2 composite and its photocatalytic performance
    Gao, Yu
    Zhang, Hanyan
    Lin, Junying
    Ding, Fu
    Sun, Yaguang
    Xu, Zhenhe
    Jingxi Huagong/Fine Chemicals, 2022, 39 (04): : 734 - 740
  • [43] Study on photocatalytic activity of MoS2/ZnO composite in visible light
    唐春梅
    张红燕
    张军
    OptoelectronicsLetters, 2020, 16 (06) : 446 - 450
  • [44] Preparation and Photocatalytic Performance of MoS2/MoO2 Composite Catalyst
    Dong, Daoyu
    Yan, Weitao
    Tao, Yaqiu
    Liu, Yunfei
    Lu, Yinong
    Pan, Zhigang
    MATERIALS, 2023, 16 (11)
  • [45] Study on photocatalytic activity of MoS2/ZnO composite in visible light
    Tang, Chun-mei
    Zhang, Hong-yan
    Zhang, Jun
    OPTOELECTRONICS LETTERS, 2020, 16 (06) : 446 - 450
  • [46] Study on photocatalytic activity of MoS2/ZnO composite in visible light
    Chun-mei Tang
    Hong-yan Zhang
    Jun Zhang
    Optoelectronics Letters, 2020, 16 : 446 - 450
  • [47] Improved photocatalytic degradation of organic dye using Ag3PO4/MoS2 nanocomposite
    Madhulika Sharma
    Pranab Kishore Mohapatra
    Dhirendra Bahadur
    Frontiers of Materials Science, 2017, 11 : 366 - 374
  • [48] Fabrication of Ternary MoS2/CdS/Bi2S3-Based Nano Composites for Photocatalytic Dye Degradation
    Nazir, Asif
    Tahir, Muhammad Suleman
    Kamal, Ghulam Mustafa
    Zhang, Xu
    Tahir, Muhammad Bilal
    Jiang, Bin
    Safdar, Muhammad
    MOLECULES, 2023, 28 (07):
  • [49] Enhanced piezo-photocatalytic performance of HPMC connected MoS2/ BiOBr for accelerating the degradation of organic pollutants
    Yao, Ziyu
    Su, Zhizhong
    Song, Jun
    Gao, Xiang
    Wang, Fang
    Wang, Yupeng
    MATERIALS LETTERS, 2025, 379
  • [50] Nanotheranostic fabrication of iron oxide for rapid photocatalytic degradation of organic dyes and antifungal potential
    Inam, Hina
    Fatima, Urooj
    Shahid, Sammia
    Mansoor, Sana
    Yasin, Amina
    Javed, Mohsin
    Iqbal, Shahid
    Alhujaily, Ahmad
    Althobiti, Randa A.
    Alzahrani, Eman
    Farouk, Abd-ElAziem
    Almufarij, Rasmiah S.
    Elkaeed, Eslam B.
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2023, 27 (05)