One-pot synthesis of HKUST-1 monolith for CO2 adsorption

被引:0
|
作者
Sakai, Motomu [1 ]
Ito, Ayaka [1 ]
Matsumoto, Takaya [2 ]
Matsukata, Masahiko [1 ,3 ,4 ]
机构
[1] Waseda Univ, Dept Appl Chem, 513 Wasedatsurumaki Cho,Shinjuku Ku, Tokyo 1620041, Japan
[2] ENEOS Corp, Cent Tech Res Lab, 8 Chidoricho,Naka Ku, Yokohama, Kanagawa 2310815, Japan
[3] Waseda Univ, Res Org Nano & Life Innovat, 513 Wasedatsurumaki Cho,Shinjuku Ku, Tokyo 1620041, Japan
[4] Waseda Univ, Adv Res Inst Sci & Engn, 3-4-1 Okubo,Shinjuku Ku, Tokyo 1698555, Japan
关键词
adsorption; carbon dioxide; HKUST-1; metal-organic framework; METAL-ORGANIC FRAMEWORKS; SEPARATION;
D O I
10.1093/chemle/upae109
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Shape-forming technology is essential for the widespread utilization of metal-organic frameworks. We developed a one-pot synthesis method for an HKUST-1 monolith. An HKUST-1 monolith was successfully prepared by the hydrothermal treatment of a Cu monolith in an aqueous solution of 1,3,5-benzenetricarboxylic acid, ethanol, and nitric acid without the addition of a metal source. The prepared HKUST-1 monolith showed CO2 adsorption properties comparable to those of commercially available HKUST-1 powdery crystals.
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页数:4
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