Conversion of Methane to Graphite-Like Carbon Nanoparticles Using a Low-Temperature Dusty Plasma

被引:0
|
作者
Belamkar, Aishwarya [1 ]
Wagner, Brandon [2 ]
Kim, Minseok [1 ]
Bermudez, Fernando [1 ]
Mangolini, Lorenzo [1 ,2 ]
机构
[1] Univ Calif Riverside, Mech Engn Dept, Riverside, CA 92521 USA
[2] Univ Calif Riverside, Mat Sci & Engn Program, Riverside, CA 92521 USA
关键词
methane conversion; carbon nanoparticles; plasmaprocess; electrification; battery materials; GAS-PHASE PHYSICS; NONTHERMAL PLASMA; FABRICATION; NANOTUBES; GRADES; FLAKES;
D O I
10.1021/acsanm.4c01614
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We utilize a dual plasma system to convert methane into graphite-like (turbostratic) carbon particles. A first plasma reactor nucleates seed carbon nanoparticles from precursors such as acetylene or toluene vapor. The seed particles are then injected into a second plasma, supplemented by methane gas. The addition of the seed particles greatly improves the conversion of methane into carbon nanoparticles. We have used the material as a conductive additive in lithium-ion battery anodes and found their performance to be comparable to that of commercial carbon black. This approach is one of the most energy-efficient plasma-based approaches to carbon black synthesis at the laboratory scale.
引用
收藏
页码:11053 / 11058
页数:6
相关论文
共 50 条
  • [31] METHANE ADSORBED ON GRAPHITE .4. MULTILAYER GROWTH AT LOW-TEMPERATURE
    PHILLIPS, JM
    HRUSKA, CD
    [J]. PHYSICAL REVIEW B, 1989, 39 (08): : 5425 - 5435
  • [32] Synthesis of ultra dispersed graphite-like structures doped with nitrogen in supersonic carbon plasma flow
    Sivkov, A.
    Pak, A.
    Shanenkov, I.
    Kolganova, J.
    Shatrova, K.
    [J]. 20TH INTERNATIONAL CONFERENCE FOR STUDENTS AND YOUNG SCIENTISTS: MODERN TECHNIQUES AND TECHNOLOGIES (MTT'2014), 2014, 66
  • [33] Determination of the gas temperature and the density of easily ionized atoms in a low-temperature dusty plasma
    Samarian, AA
    Chernyshev, AV
    Nefedov, AP
    Petrov, OF
    [J]. PLASMA PHYSICS REPORTS, 1999, 25 (11) : 912 - 916
  • [34] Study of evaporating the irradiated graphite in equilibrium low-temperature plasma
    Bespala, E. V.
    Novoselov, I. Yu.
    Pavlyuk, A. O.
    Kotlyarevskiy, S. G.
    [J]. THERMOPHYSICS AND AEROMECHANICS, 2018, 25 (01) : 109 - 117
  • [35] Study of evaporating the irradiated graphite in equilibrium low-temperature plasma
    E. V. Bespala
    I. Yu. Novoselov
    A. O. Pavlyuk
    S. G. Kotlyarevskiy
    [J]. Thermophysics and Aeromechanics, 2018, 25 : 109 - 117
  • [36] LOW-TEMPERATURE DIAMOND GROWTH AND PLASMA SPECIES ANALYSIS USING METHANE-CARBON DIOXIDE GAS-MIXTURES
    CHEN, CF
    CHEN, SH
    HONG, TM
    WANG, DP
    [J]. SCRIPTA METALLURGICA ET MATERIALIA, 1994, 31 (06): : 775 - 780
  • [37] Chiral recognition of penicillamine enantiomers using hemoglobin and gold nanoparticles functionalized graphite-like carbon nitride nanosheets via electrochemiluminescence
    Lin, Xia
    Zhu, Shu
    Wang, Qinghong
    Xia, Qiao
    Ran, Peiyao
    Fu, Yingzi
    [J]. COLLOIDS AND SURFACES B-BIOINTERFACES, 2016, 148 : 371 - 376
  • [38] Low-Temperature Steam Conversion of Natural Gas to Methane–Hydrogen Mixtures
    D. I. Potemkin
    S. I. Uskov
    A. M. Gorlova
    V. A. Kirillov
    A. B. Shigarov
    A. S. Brayko
    V. N. Rogozhnikov
    P. V. Snytnikov
    A. A. Pechenkin
    V. D. Belyaev
    A. A. Pimenov
    V. A. Sobyanin
    [J]. Catalysis in Industry, 2020, 12 : 244 - 249
  • [39] Synthesis of metal-carbon nanocomposites containing nanoparticles of transition metals encapsulated in a graphite-like shell
    Kryazhev, Yu. G.
    Zapevalova, E. S.
    Semenova, O. N.
    Trenikhin, M. V.
    Solodovnichenko, V. S.
    Likholobov, B. A.
    [J]. PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2017, 53 (02) : 268 - 271
  • [40] On the low-temperature plasma discharge in methane air diffusion flames
    Zare, Saeid
    Lo, Hao Wei
    Roy, Shrabanti
    Askari, Omid
    [J]. ENERGY, 2020, 197