1,4-Diazabicyclo[2.2.2]octane (DABCO) in Organic Synthesis and Catalysis: A Quinquennial Report (2019-to date)

被引：1

作者：

Varala, Ravi ^{[1
,2
]}

Seema, Vittal ^{[3
]}

Alam, Mohammed Mujahid ^{[4
]}

Amanullah, Mohammed ^{[5
]}

Prasad, Beda Durga ^{[6
]}

机构：

[1] Scrips Pharm, Hyderabad 500076, Telangana, India

[2] INTI Int Univ, Nilai, Malaysia

[3] RGUKT Basar, Dept Chem, Mudhole 504107, Telangana, India

[4] King Khalid Univ, Coll Sci, Dept Chem, Abha, Saudi Arabia

[5] King Khalid Univ, Coll Med, Dept Clin Biochem, Abha, Saudi Arabia

[6] GITAM Hyderabad Campus, Dept Pharmaceut Chem, Rudraram, Telangana, India

来源：

CURRENT ORGANIC CHEMISTRY | 2024年 / 28卷 / 17期

关键词：

DABCO; base; organocatalyst; catalysis; organic synthesis; C-H Functionalization; heterocyclic ring formation; annulations; cyclization; rearrangement; H BOND FUNCTIONALIZATION; EFFICIENT SYNTHESIS; BIOLOGICAL EVALUATION; MOLECULAR DOCKING; IONIC LIQUID; DERIVATIVES; BASE; ACID; ORGANOCATALYSIS; SUBSTITUENTS;

D O I：

10.2174/0113852728313865240528073519

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

DABCO is one of the more effective basic organocatalysts/reagents that can be used for a range of organic transformations, including C-H functionalization, formation of hetero-hetero bonds, rearrangements, the synthesis of heterocyclic compounds, cyclizations and annulations, other miscellaneous reactions. This quinquennial review aims to critically and perceptively address noteworthy contributions of non chiral catalyst DABCO for regular organic transformations from 2019 onward. The key areas of attention were the advantages and limits of the approach, in addition to the mechanistic pathway, which is required for a specific organic transformation to be performed effectively.

引用

页码：1307 / 1345

页数：39

共 50 条

[41] Synthesis and Characterisation of Iodobismuthates Containing N-substituted 1,4-Diazabicyclo[2.2.2]octane
Yunhe Cai
Ann M. Chippindale
Paz Vaqueiro
Journal of Chemical Crystallography, 2023, 53 : 167 - 176
[42] Reoriention of diprotonated DABCO (1,4-Diazabicyclo[2.2.2]octane) cation and proton transfer in organic ferroelectric adduct DABCO-2(2-Chlorobenzoic acid)
Asaji, Tetsuo
JOURNAL OF MOLECULAR STRUCTURE, 2018, 1159 : 174 - 178
[43] Synthesis of Chiral 2,3-Disubstituted 1,4-Diazabicyclo[2.2.2]octane Derivatives
Periasamy, Mariappan
Edukondalu, Athukuri
Reddy, Polimera Obula
JOURNAL OF ORGANIC CHEMISTRY, 2015, 80 (07): : 3651 - 3655
[44] Synthesis and Characterisation of Iodobismuthates Containing N-substituted 1,4-Diazabicyclo[2.2.2]octane
Cai, Yunhe
Chippindale, Ann M.
Vaqueiro, Paz
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2023, 53 (01) : 167 - 176
[45] SYNTHESIS AND CHARACTERIZATION OF 1,4-DIAZABICYCLO[2.2.2] OCTANE AND PIPERIDINE ADDUCTS OF DIVALENT TIN HALIDES
DEANS, RA
GEANANGEL, RA
INORGANICA CHIMICA ACTA-ARTICLES, 1980, 43 (02): : 159 - 163
[46] Self condensation of methyl acetopyruvate in the presence of 1,4-diazabicyclo[2.2.2]octane
Lee, HJ
Kim, TY
Kim, JN
SYNTHETIC COMMUNICATIONS, 1999, 29 (24) : 4375 - 4379
[47] Reverse sequence of transitions in prototypic relaxor 1,4-diazabicyclo[2.2.2]octane
Nowicki, Waldemar
Olejniczak, Anna
Andrzejewski, Michal
Katrusiak, Andrzej
CRYSTENGCOMM, 2012, 14 (20) : 6428 - 6434
[48] Synthesis of Bicyclic ortho-Aminocarbonitrile Derivatives Catalyzed by 1,4-Diazabicyclo[2.2.2]octane
Yan, Shiqiang
Dong, Daoqing
Xie, Chunwen
Wang, Wensheng
Wang, Zuli
CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2019, 39 (09) : 2560 - 2566
[49] HYDROXYALKYLATION OF METHYLVINYL KETONES AND ACRYLONITRILE IN THE PRESENCE OF 1,4-DIAZABICYCLO[2.2.2]OCTANE
AMRI, H
VILLIERAS, J
TETRAHEDRON LETTERS, 1986, 27 (36) : 4307 - 4308
[50] 1,4-Diazabicyclo[2.2.2]octane Bis(sulfur dioxide) Adduct (DABSO)
Martial, Ludovic
SYNLETT, 2013, 24 (12) : 1595 - 1596

← 1 2 3 4 5 →