Influence of the oxidic support material on the platinum-catalyzed benzyl alcohol oxidation

被引：0

作者：

Kunene, Avela ^{[1
,2
]}

van Steen, Eric ^{[1
]}

机构：

[1] Univ Cape Town, Catalysis Inst, Dept Chem Engn, Private Bag X3, ZA-7701 Rondebosch, South Africa

[2] Helmholtz Zentrum Berlin Materialien & Energie, Hahn Meitner Pl 1, D-14109 Berlin, Germany

来源：

ARKIVOC | 2024年

关键词：

Aerobic; oxidation; benzyl alcohol; platinum; support; FISCHER-TROPSCH SYNTHESIS; SELECTIVE OXIDATION; AEROBIC OXIDATION; OXYGEN VACANCY; WATER; PD; REDUCIBILITY; INTERFACES;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Platinum supported on different oxides is an effective catalyst for the benzyl alcohol oxidation, but the type of support material affects the overall catalytic performance. Here, the performance of dispersed platinum nanoparticles in range of 2.5-4.6 nm supported on reducible oxides (TiO2 (P25), CeO2, MoO3 and gamma-Fe2O3) and an irreducible oxide(gamma-Fe2O3) is investigated for the application of benzyl alcohol oxidation catalysts in the presence of liquid water. The difference in the performance is attributed to the ability of the support to accept hydrogen from benzyl alcohol adsorbed on platinum and the ability to remove surface hydroxyl groups in the form of water. [GRAPHICS] .

引用

页数：12

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