Production of High-Coercive nanostructured Nd-Fe-B alloy by chemical method

For the first time, a nanostructured alloy powder with high coercive force was obtained by a chemical method without the addition of Dy, which can compete with physical methods of production. The work carried out a study of the influence of stoichiometric composition on the magnetic properties of nanostructured Nd-Fe-B alloys. Alloys with different contents of Nd, Fe, and B were synthesized: Nd12Fe84B6, Nd14Fe80B6, Nd16Fe76B8, and Nd16Fe72B8. With a decrease in the iron content in the first two compositions, a decrease in the iron content in the soft magnetic phase alpha-Fe was observed, which led to an increase in the coercive force Hc and a decrease in the values of M-s and M-r. Experiments have shown that an increase in the content of Nd and B promotes the formation of the hard magnetic phase Nd2Fe14B and an increase in the coercive force. For example, the nanostructured Nd16Fe76B8 alloy demonstrated a maximum coercive force of H-c = 8439 Oe, while compensating for the values of M-s (109 emu*g(-1)) and M-r (78 emu*g(-1)). A comprehensive study of the nanostructured Nd16Fe76B8 alloy was carried out, including structural analysis. XRD using FullProff and Vesta software revealed the tetragonal crystal structure of the Nd2Fe14B phase, providing details of the atomic arrangement. The unit cell contains four layers with Nd and Fe atoms, and boron atoms are embedded in the center of the octahedron of Nd and Fe atoms, playing an important role in the magnetic exchange interaction. The results of Mossbauer spectroscopy confirmed the presence of the Nd2Fe14B phase and revealed details of the state of Fe atoms in the structure of six sextets.