Single-Electron Oxidation-Induced Chemical Transformations: Carbon-Carbon Bond Formation and Selective Oxaziridine Rearrangement

被引：0
|
作者：
Atriardi, Shafrizal Rasyid [1 ]
Woo, Sang Kook [1 ]
机构：
[1] Univ Ulsan, Dept Chem, 93 Daehak Ro, Ulsa 44610, South Korea
来源：
ALDRICHIMICA ACTA | 2023年 / 56卷 / 01期
基金：
新加坡国家研究基金会;
关键词：
visible light; photoredox catalysis; single-electron transfer (SET); silicon-based radical precursor; Giese reaction; oxaziridine rearrangement; PMP deprotection; PHOTOREDOX CATALYSIS; ORGANOSILICON COMPOUNDS; DEFICIENT ALKENES; LIGHT; GENERATION; FLUORINE; FUNCTIONALIZATION; CYCLOADDITION; PRECURSORS; RADICALS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Visible -light photoredox catalysis is an important and growing research area in the field of green and sustainable organic synthesis. One of the main mechanisms involved in photoredox catalysis is single -electron transfer (SET), which has been extensively investigated in our group for the development of greener carbon-carbon bond forming reactions and oxaziridine rearrangement. In this review, we highlight our results on the development and application of neutral silicon radical precursors for the generation of alkyl radicals and the selective rearrangement of oxaziridines into nitrones or amides.
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页数：50
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