Crystal structure optimization of copper oxides for the benzyl alcohol oxidation reaction

被引：2

作者：

Sun, Hainan ^{[1
,2
]}

Li, Lili ^{[3
,4
]}

Chen, Yahui ^{[5
]}

Kim, Yong Beom ^{[2
]}

Kim, Hyunseung ^{[2
]}

Fei, Liangshuang ^{[6
]}

Shao, Zongping ^{[7
]}

Jung, WooChul ^{[2
]}

机构：

[1] Nantong Univ, Sch Chem & Chem Engn, Nantong 226019, Peoples R China

[2] Korea Adv Inst Sci & Technol KAIST, Dept Mat Sci & Engn, Daejeon 34141, South Korea

[3] Shandong Univ, State Key Lab Crystal Mat, Jinan 250100, Peoples R China

[4] Shandong Univ, Inst Crystal Mat, Jinan 250100, Peoples R China

[5] Shenzhen Univ, Coll Mat Sci & Engn, State Key Lab Fine Chem, Shenzhen 518071, Peoples R China

[6] Nanjing Tech Univ, Coll Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 211816, Peoples R China

[7] Curtin Univ, WA Sch Mines Minerals Energy & Chem Engn WASM MECE, Perth, WA 6102, Australia

来源：

CHEMICAL COMMUNICATIONS | 2024年 / 60卷 / 56期

基金：

新加坡国家研究基金会;

关键词：

NI;

D O I：

10.1039/d4cc01751j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this work, experimental and theoretical analyses reveal that different types of Cu wires significantly change the adsorption properties of reactant molecules and the benzyl alcohol oxidation reaction performance. In particular, CuO nanowires in situ grown on Cu foam exhibit the best performance with a low potential of 1.39 V at a current density of 200 mA cm-2, high selectivity to benzoic acid production, and good operational stability. Experimental and theoretical analyses show Cu-based wires alter adsorption properties, affecting benzyl alcohol oxidation. CuO nanowires show high performance toward benzyl alcohol oxidation reaction.

引用

页码：7224 / 7227

页数：4

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