Recycling of waste silicon powder from the photovoltaic industry into high performance porous Si@void@carbon anodes for Li-ion battery

To enhance the performance of lithium -ion battery anodes, this study leverages recycled diamond wire -cut silicon particles, a byproduct of the photovoltaic sector. These particles undergo purification through acid wash and pyrolysis to eliminate contaminants, thereby serving as potential anode materials. The inherent challenge with silicon involves its significant volumetric expansion during lithiation and delithiation, which hampers its viability for commercial applications. Addressing this, the research introduces a facile approach by synthesizing porous silicon (pSi) via the Ag-assisted chemical etching method. Subsequently, a distinctive yolk -shell porous silicon@void@carbon (pSi@V@C) structure is created using a sacrificial template approach, ensuring the formation of voids between the porous silicon core and the carbon shell. This configuration mitigates the detrimental effects of silicon 's volume expansion while enhancing electrical conductivity through the carbon shell. The pSi@V@C composite exhibits promising electrochemical performance, demonstrated by an initial discharge capacity of 1826 mAh g -1 and a Coulombic efficiency of 68.6% at 0.1 A g -1 . Remarkably, it maintains a capacity of 821.8 mAh g -1 after 550 cycles at 1 A g -1 , with a retention rate of 90.4%.