Recent developments in materials and applications of triplet dynamic nuclear polarization

被引：3

作者：

Hamachi, Tomoyuki ^{[1
]}

Yanai, Nobuhiro ^{[1
,2
]}

机构：

[1] Grad Sch Engn, Dept Appl Chem, 744 Moto Oka,Nishi Ku, Fukuoka 8190395, Japan

[2] CREST, JST, Honcho 4-1-8, Kawaguchi, Saitama 3320012, Japan

来源：

PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY | 2024年 / 142卷

关键词：

Photoexcited triplet state; Dynamic Nuclear Polarization (DNP); Triplet-DNP; Dissolution triplet-DNP; Electron Spin Resonance (ESR); PHOTO-EXCITED TRIPLET; PROTON POLARIZATION; HYPERPOLARIZED WATER; ELECTRON SPINS; STATE; PENTACENE; CHEMISTRY;

D O I：

10.1016/j.pnmrs.2024.05.001

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dynamic nuclear polarization (DNP) is a method for achieving high levels of nuclear spin polarization by transferring spin polarization from electrons to nuclei by microwave irradiation, resulting in higher sensitivity in NMR/MRI. In particular, DNP using photoexcited triplet electron spins (triplet-DNP) can provide a hyperpolarized nuclear spin state at room temperature and in low magnetic field. In this review article, we highlight recent developments in materials and instrumentation for the application of triplet-DNP. First, a brief history and principles of triplet-DNP will be presented. Next, important advances in recent years will be outlined: new materials to hyperpolarize water and biomolecules; high -sensitivity solution NMR by dissolution triplet-DNP; and strategies for further improvement of the polarization. In view of these developments, future directions to widen the range of applications of triplet-DNP will be discussed.

引用

页码：55 / 68

页数：14

共 50 条

[41] Recent applications of nuclear microprobe analysis to frontier materials
Jamieson, DN
NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 1997, 130 (1-4): : 706 - 716
[42] RECENT DEVELOPMENTS AND CURRENT PROBLEMS IN INORGANIC ANALYTICAL CHEMISTRY - NUCLEAR MATERIALS
RODDEN, CJ
ANALYTICAL CHEMISTRY, 1959, 31 (12) : 1940 - 1945
[43] Perspective of Overhauser dynamic nuclear polarization for the study of soft materials
Biller, Joshua R.
Barnes, Ryan
Han, Songi
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2018, 33 : 72 - 85
[44] RECENT DEVELOPMENTS ON ISOL TARGETS FOR THE SPES PROJECT FOR NUCLEAR PHYSICS AND APPLICATIONS
Corradetti, S.
Borgna, F.
Ballan, M.
Biasetto, L.
Carturan, S.
Manzolaro, M.
Innocentini, M. D. M.
Colombo, P.
Andrighetto, A.
PROCEEDINGS OF THE 12TH PACIFIC RIM CONFERENCE ON CERAMIC AND GLASS TECHNOLOGY, 2018, 264 : 245 - 251
[45] Dynamic Nuclear Polarization (DNP) 101: A New Era for Materials
Hooper, Riley W.
Klein, Brittney A.
Michaelis, Vladimir K.
CHEMISTRY OF MATERIALS, 2020, 32 (11) : 4425 - 4430
[46] Dynamic Nuclear Polarization of Metal-Organic Frameworks Using Photoexcited Triplet Electrons
Tateishi, Kenichiro (kenichiro.tateishi@riken.jp), 1600, American Chemical Society (140):
[47] INDUCED DYNAMIC NUCLEAR SPIN POLARIZATION IN REACTIONS OF PHOTOCHEMICALLY AND THERMALLY GENERATED TRIPLET DIPHENYLMETHYLENE
CLOSS, GL
CLOSS, LE
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1969, 91 (16) : 4549 - &
[48] CHEMICALLY INDUCED DYNAMIC NUCLEAR POLARIZATION - TRIPLET AND SINGLET STATE PHOTOSENSITIZATION OF PEROXIDE DECOMPOSITIONS
KAPTEIN, R
DENHOLLA.JA
ANTHEUNI.D
OOSTERHO.LJ
JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1970, (24): : 1687 - &
[49] RECENT ADVANCES IN FLAME RETARDANCY OF POLYMERIC MATERIALS (MATERIALS, APPLICATIONS, INDUSTRY DEVELOPMENTS, MARKETS)
ZAIKOV, GE
ARTSIS, MI
OXIDATION COMMUNICATIONS, 1995, 18 (03): : 326 - 330
[50] Recent advances in flame retardancy of polymeric materials: Materials, applications, industry developments, markets
Zaikov, GE
Artsis, MI
INTERNATIONAL JOURNAL OF POLYMERIC MATERIALS, 1995, 28 (1-4) : 129 - 133

← 1 2 3 4 5 →