Gold content determination in small core-samples by instrumental neutron activation analysis

Application of instrumental neutron activation analysis (INAA) based on the relative method of concentration standardization was considered to determine Au content in small solid core-samples of the gold-bearing ores and rocks up to 10 g of the mass. The small core-samples about 10 mm in diameter and 22-23 mm in length were cut from the previously collected ore lumps or in-situ using a handheld drilling rig. The studied small core-samples and the polyethylene capsules of the same dimensions filled up with the corresponding certified reference material (CRM) were irradiated for 2 min by a lower density neutron flux with the help of the automated pneumatic transport system (PTS). Maximum mass and dimensions of the core-samples corresponded to the PTS design and to the conditions of its safe operation. A special device was made to fix the transport capsules in the stable counting geometry making possible to eliminate the influence of the neutron flux gradient during irradiation. Due to the substantial differences in CRM and solid sample densities, corrections for neutron self-shielding and for gamma-ray self-absorption by the core-samples were applied. The method was tried to analyze Au content in 170 small core-samples presenting different gold-bearing ores and country rocks from the Kazakhstan's gold-barite-polymetallic deposit Maikain. This approach, rather simple methodically and requiring no unique equipment, can be used to assess gold resources together with the methods of geostatistics.