Miracle in "White":Hexagonal Boron Nitride

被引:7
|
作者
Wang, Jiaqi [1 ]
Xu, Tongzhou [1 ]
Wang, Weipeng [1 ]
Zhang, Zhengjun [1 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, Key Lab Adv Mat, MOE, Beijing 10084, Peoples R China
关键词
hexagonal boron-nitride; passivation coating; thermal management; unity of the contradictions; ultra-flat surface; FIELD-EFFECT TRANSISTORS; GRAPHENE; REMOVAL; DEGRADATION; PERFORMANCE; TRANSPORT; COATINGS; FIBERS; FILMS; IONS;
D O I
10.1002/smll.202400489
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The exploration of 2D materials has captured significant attention due to their unique performances, notably focusing on graphene and hexagonal boron nitride (h-BN). Characterized by closely resembling atomic structures arranged in a honeycomb lattice, both graphene and h-BN share comparable traits, including exceptional thermal conductivity, impressive carrier mobility, and robust pi-pi interactions with organic molecules. Notably, h-BN has been extensively examined for its exceptional electrical insulating properties, inert passivation capabilities, and provision of an ideal ultraflat surface devoid of dangling bonds. These distinct attributes, contrasting with those of h-BN, such as its conductive versus insulating behavior, active versus inert nature, and absence of dangling surface bonds versus absorbent tendencies, render it a compelling material with broad application potential. Moreover, the unity of such contradictions endows h-BN with intriguing possibilities for unique applications in specific contexts. This review aims to underscore these key attributes and elucidate the intriguing contradictions inherent in current investigations of h-BN, fostering significant insights into the understanding of material properties. The concepts of '' Yin '' and '' Yang '' symbolizes the interplay of opposites such as heaven and earth. By employing the metaphor of '' yin '' and '' yang,'' parallels are drawn to the seemingly contradictory properties observed in hexagonal-boron nitride, where these paired properties are perceived as inherently opposite to each other. The understanding and manipulation of these contradictions would lead to a unity of opposites, which will find applications in unique circumstances. image
引用
收藏
页数:17
相关论文
共 50 条
  • [41] Adsorption of Hexacontane on Hexagonal Boron Nitride
    Albar, Juan D.
    Korolkov, Vladimir V.
    Baldoni, Matteo
    Watanabe, Kenji
    Taniguchi, Takashi
    Besley, Elena
    Beton, Peter H.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2018, 122 (48): : 27575 - 27581
  • [42] NORMAL MODES IN HEXAGONAL BORON NITRIDE
    GEICK, R
    PERRY, CH
    RUPPRECH.G
    PHYSICAL REVIEW, 1966, 146 (02): : 543 - &
  • [43] Synthesis of powdered hexagonal boron nitride
    Avdeev, OV
    Shevchenko, SA
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 1996, 69 (07) : 940 - 942
  • [44] Evolution of nanopores in hexagonal boron nitride
    Dai, Chunhui
    Popple, Derek
    Su, Cong
    Park, Ji-Hoon
    Watanabe, Kenji
    Taniguchi, Takashi
    Kong, Jing
    Zettl, Alex
    COMMUNICATIONS CHEMISTRY, 2023, 6 (01)
  • [45] Mechanical Hysteresis of Hexagonal Boron Nitride
    Zhou Aiguo
    Li Haoran
    JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2011, 26 (05): : 935 - 938
  • [46] Hexagonal boron nitride cavity optomechanics
    Shandilya, Prasoon K.
    Froch, Johannes E.
    Mitchell, Matthew
    Lake, David P.
    Kim, Sejeong
    Toth, Milos
    Behera, Bishnupada
    Healey, Chris
    Aharonovich, Igor
    Barclay, Paul E.
    2019 CONFERENCE ON LASERS AND ELECTRO-OPTICS (CLEO), 2019,
  • [47] Vacancy migration in hexagonal boron nitride
    Zobelli, A.
    Ewels, C. P.
    Gloter, A.
    Seifert, G.
    PHYSICAL REVIEW B, 2007, 75 (09)
  • [48] THE INTERACTION OF ARGON WITH HEXAGONAL BORON NITRIDE
    PIEROTTI, RA
    PETRICCIANI, JC
    JOURNAL OF PHYSICAL CHEMISTRY, 1960, 64 (10): : 1596 - 1597
  • [49] Helical nanotubes of hexagonal boron nitride
    Terauchi, Masami
    Tanaka, Michiyoshi
    Matsuda, Hirofumi
    Takeda, Masatoshi
    Kimura, Kaoru
    Microscopy, 1997, 46 (01): : 75 - 78
  • [50] Polymer Brushes on Hexagonal Boron Nitride
    Sheng, Wenbo
    Amin, Ihsan
    Neumann, Christof
    Dong, Renhao
    Zhang, Tao
    Wegener, Erik
    Chen, Wei-Liang
    Foerster, Paul
    Hai Quang Tray
    Loeffler, Markus
    Winter, Andreas
    Rodriguez, Raul D.
    Zschech, Ehrenfried
    Ober, Christopher K.
    Feng, Xinliang
    Turchanin, Andrey
    Jordan, Rainer
    SMALL, 2019, 15 (19)