Superior Electrochemical Performance and Cyclic Stability of WS2@CoMgS//AC Composite on the Nickel-Foam for Asymmetric Supercapacitor Devices

被引:3
|
作者
Imran, Muhammad [1 ]
Afzal, Amir Muhammad [1 ]
Iqbal, Muhammad Waqas [1 ]
Mumtaz, Sohail [2 ]
Alqarni, Areej S. [3 ]
机构
[1] Riphah Int Univ, Dept Phys, Campus Lahore, Lahore 54000, Pakistan
[2] Kwangwoon Univ, Dept Elect & Biol Phys, Seoul 01897, South Korea
[3] Princess Nourah Bint Abdulrahman Univ, Coll Sci, Dept Biol, POB 84428, Riyadh 11671, Saudi Arabia
关键词
2D-TMDs; tungsten disulfide; cobalt magnesium sulfide; energy storage; redox active cites; cyclic stability; ELECTRODE MATERIAL; ENERGY-STORAGE; NANOSHEETS; HETEROSTRUCTURES; CHALLENGES; GRAPHENE;
D O I
10.3390/en17143363
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
Two-dimensional (2D) sulfide-based transition metal dichalcogenides (TMDs) have shown their crucial importance in energy storage devices. In this study, the tungsten disulfide (WS2) nanosheets were combined with hydrothermally synthesized cobalt magnesium sulfide (CoMgS) nanocomposite for use as efficient electrodes in supercapattery energy storage devices. The characteristics of the WS2@CoMgS nanocomposite were better than those of the WS2 and CoMgS electrodes. XRD, SEM, and BET analyses were performed on the nanocomposite to examine its structure, morphology, and surface area in depth. In three-electrode assemblies, the composite (WS2@CoMgS) electrode showed a high specific capacity of 874.39 C g(-1) or 1457.31 F g(-1) at 1.5 A g(-1). The supercapattery device (WS2@CoMgS//AC) electrode demonstrated a specific capacity of 325 C g(-1) with an exceptional rate capability retention of 91% and columbic efficiency of 92% over 7000 cycles, according to electrochemical studies. Additionally, the high energy storage capacity of the WS2@CoMgS composite electrode was proved by structural and morphological investigations.
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页数:15
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