Flexible Co3O4/TiO2 monolithic catalysts for low-temperature and long-term stable CO oxidation

被引:4
|
作者
Tang, Xinyue [1 ,2 ]
Wang, Junchao [1 ]
Ma, Yonghui [3 ]
Li, Jing [1 ]
Zhang, Xinglai [1 ]
La, Peiqing [4 ]
Liu, Baodan [1 ]
机构
[1] Chinese Acad Sci, Shenyang Natl Lab Mat Sci SYNL, Inst Met Res IMR, 72 Wenhua Rd, Shenyang 110016, Peoples R China
[2] Univ Sci & Technol China, Sch Mat Sci & Engn, 72 Wenhua Rd, Shenyang 110016, Peoples R China
[3] Chinese Acad Sci, Inst Met Res, Struct Anal Div, Shenyang 110016, Peoples R China
[4] Lanzhou Univ Technol, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
来源
NANO SELECT | 2021年 / 2卷 / 01期
关键词
CO oxidation; Co3O4/TiO2; flexible monolithic catalysts; in-situ growth; long-term stability; IN-SITU FABRICATION; PERFORMANCE; EFFICIENT; NANOSHEETS;
D O I
10.1002/nano.202000112
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The development of efficient monolithic catalysts and their fabrication methods for low-temperature and long-term stable CO oxidation always remains a challenge for both fundamental research and technological application. In this work, an innovative synthetic strategy to in-situ integrate Co3O4/TiO2 monolithic catalysts on flexible Ti mesh substrate through multi-step processes was demonstrated. The in-situ grown catalysts show strong substrate adhesion, large surface areas and a complete CO conversion temperature of 105 degrees C, which is superior or comparative to most noble metal catalysts. The in-situ grown Co3O4/TiO2 catalysts on Ti mesh also exhibit excellent long-term stability that is critically important for industrial application. It is expected that the in-situ synthesis strategy of well-defined Co3O4/TiO2 monolithic catalysts on flexible mesh substrate can be extended to the development of a variety of oxide-based monolithic catalysts towards diverse catalysis applications.
引用
收藏
页码:72 / 82
页数:11
相关论文
共 50 条
  • [21] Mesoporous Co3O4 supported Pt catalysts for low-temperature oxidation of acetylene
    Wang, Qi
    Liu, Jian
    Li, Yongheng
    Zhao, Zhen
    Song, Weiyu
    Wei, Yuechang
    [J]. RSC ADVANCES, 2017, 7 (30): : 18592 - 18600
  • [22] Porous Co3O4 nano-array based monolithic catalysts for low temperature CO and hydrocarbon oxidation
    Ren, Zheng
    Wang, Sibo
    Botu, Venkatesh
    Ramprasad, Rampi
    Gao, Puxian
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [23] Fabrication of high-performance CeO2-MnOx/TiO2/Ti monolithic catalysts for low-temperature and stable CO oxidation
    Wang, Junchao
    Tang, Xinyue
    Li, Jing
    Dong, Shizhi
    Zhang, Xinglai
    Liu, Baodan
    [J]. CATALYSIS SCIENCE & TECHNOLOGY, 2023, 13 (11) : 3386 - 3394
  • [24] INFLUENCE OF DRY OPERATING-CONDITIONS - OBSERVATION OF OSCILLATIONS AND LOW-TEMPERATURE CO OXIDATION OVER CO3O4 AND AU/CO3O4 CATALYSTS
    CUNNINGHAM, DAH
    KOBAYASHI, T
    KAMIJO, N
    HARUTA, M
    [J]. CATALYSIS LETTERS, 1994, 25 (3-4) : 257 - 264
  • [25] Synthesis and characterization of CuO/TiO2 catalysts for low-temperature CO oxidation
    Huang, Jing
    Wang, Shurong
    Zhao, Yingqiang
    Wang, Xiaoying
    Wang, Shuping
    Wu, Shihua
    Zhang, Shoumin
    Huang, Weiping
    [J]. CATALYSIS COMMUNICATIONS, 2006, 7 (12) : 1029 - 1034
  • [26] Origin of the High Activity and Stability of Co3O4 in Low-temperature CO Oxidation
    Yong-Zhao Wang
    Yong-Xiang Zhao
    Chun-Guang Gao
    Dian-Sheng Liu
    [J]. Catalysis Letters, 2008, 125 : 134 - 138
  • [27] Origin of the high activity and stability of Co3O4 in low-temperature CO oxidation
    Wang, Yong-Zhao
    Zhao, Yong-Xiang
    Gao, Chun-Guang
    Liu, Dian-Sheng
    [J]. CATALYSIS LETTERS, 2008, 125 (1-2) : 134 - 138
  • [28] Low-temperature CO oxidation by Co3O4 nanocubes on the surface of Ca(OH)2 nanosheets
    Lv, Shuai
    Xia, Guofu
    Jin, Chao
    Hao, Chunyu
    Wang, Li
    Li, Jinlin
    Zhang, Yuhua
    Zhu, Jun Jiang
    [J]. CATALYSIS COMMUNICATIONS, 2016, 86 : 100 - 103
  • [29] Surface characterization study of Au/alpha-Fe2O3 and Au/Co3O4 low-temperature CO oxidation catalysts
    Epling, WS
    Hoflund, GB
    Weaver, JF
    Tsubota, S
    Haruta, M
    [J]. JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (23): : 9929 - 9934
  • [30] Low-temperature CO oxidation over Co3O4-based catalysts: Significant promoting effect of Bi2O3 on Co3O4 catalyst
    Lou, Yang
    Wang, Li
    Zhao, Zhenyang
    Zhang, Yanhui
    Zhang, Zhigang
    Lu, Guanzhong
    Guo, Yun
    Guo, Yanglong
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2014, 146 : 43 - 49