Palladium(0) complexes stabilized by anionic aluminium ligands

被引：0
|
作者：
Kinjo, Rei [1 ]
Yan, Chenting [1 ]
Crimmin, Mark [1 ]
机构：
[1] Nanyang Technol Univ, Singapore, Singapore
来源：
NATURE SYNTHESIS | 2024年 / 3卷 / 07期
关键词：
D O I：
10.1038/s44160-024-00538-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Palladium can be stabilized in the zero-oxidation state with one, two or three anionic aluminium ligands to produce mono-, di- or trianionic complexes, respectively. The palladium centres in the resulting complexes are highly negatively charged, and this electron richness enables the trianionic complex to undergo a hitherto hypothetical oxidative addition reaction with a diboron species.
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收藏
页码：807 / 808
页数：2
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