Magnetic anisotropy in octahedral Dy(iii) and Yb(iii) complexes

被引：4
|
作者：
Borah, Aditya [1 ,3 ]
Dey, Sourav [1 ]
Siddiqui, Kehkasha [1 ]
Gupta, Sandeep K. [2 ]
Rajaraman, Gopalan [1 ]
Murugavel, Ramaswamy [1 ]
机构：
[1] Indian Inst Technol Bombay Powai, Dept Chem, Mumbai 400076, Maharashtra, India
[2] Indian Inst Technol Delhi, Dept Chem, Delhi 110016, India
[3] Jengraimukh Coll, Dept Chem, Majuli 785105, Assam, India
来源：
DALTON TRANSACTIONS | 2024年 / 53卷 / 17期
关键词：
SINGLE-MOLECULE MAGNET; YB-III COMPLEXES; ION MAGNETISM; LIGAND;
D O I：
10.1039/d3dt04352e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New organophosphate complexes [Ln(dippH)(3)(dippH(2))(3)]<middle dot>(H2O)(6), (Ln = Dy, Yb and Y; dippH(2) = 2,6-diisopropylphenyl phosphate), displaying octahedral coordination geometry around the metal ion, exhibit unusual slow relaxation of magnetisation, which is investigated through experimental studies and ab initio CASSCF calculations.
引用
收藏
页码：7263 / 7267
页数：5
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