Magnetic anisotropy in octahedral Dy(iii) and Yb(iii) complexes

被引：4

作者：

Borah, Aditya ^{[1
,3
]}

Dey, Sourav ^{[1
]}

Siddiqui, Kehkasha ^{[1
]}

Gupta, Sandeep K. ^{[2
]}

Rajaraman, Gopalan ^{[1
]}

Murugavel, Ramaswamy ^{[1
]}

机构：

[1] Indian Inst Technol Bombay Powai, Dept Chem, Mumbai 400076, Maharashtra, India

[2] Indian Inst Technol Delhi, Dept Chem, Delhi 110016, India

[3] Jengraimukh Coll, Dept Chem, Majuli 785105, Assam, India

来源：

DALTON TRANSACTIONS | 2024年 / 53卷 / 17期

关键词：

SINGLE-MOLECULE MAGNET; YB-III COMPLEXES; ION MAGNETISM; LIGAND;

D O I：

10.1039/d3dt04352e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New organophosphate complexes [Ln(dippH)(3)(dippH(2))(3)]<middle dot>(H2O)(6), (Ln = Dy, Yb and Y; dippH(2) = 2,6-diisopropylphenyl phosphate), displaying octahedral coordination geometry around the metal ion, exhibit unusual slow relaxation of magnetisation, which is investigated through experimental studies and ab initio CASSCF calculations.

引用

页码：7263 / 7267

页数：5

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